Use of ionic liquid based chitosan as sorbent for preconcentration of fluoroquinolones in milk, egg, fish, bovine, and chicken meat samples by solid phase extraction prior to HPLC determination

Bozkurt, Serap Seyhan; Erdoğan, Deniz Altunöz; Antep, Mine; Tüzmen, Nalan; Merdıvan, Melek

doi:10.1080/10826076.2015.1116010

Cited by 26 publications

(11 citation statements)

References 55 publications

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“…FQs have broad spectrum activity against Gram-positive and Gram-negative bacteria, and they are used in veterinary medicine for respiratory, urinary, gastrointestinal, and skin infections treat-ment (Barreto, Ribeiro, Hoff, & Costa, 2017;Chaowana & Bunkoed, 2019;. The presence of these antibiotics in meat is a health risk for humans because they can produce allergic reactions, carcinogenesis and pathogen resistance (Barreto et al, 2017;Bozkurt, Erdogan, Antep, Tuzmen, & Merdivan, 2016;. Therefore, the EU has set MRLs for some FQs in animal tissues, for example, flumequine (0.2 mg kg -1 ), marbofloxacion (0.15 mg kg -1 ), difloxacin (0.4 mg kg -1 ), ciprofloxacin (0.1 mg kg -1 ), and sarafloxacin (0.01 mg kg -1 ; Chaowana & Bunkoed, 2019; X.…”

Section: Quinolonesmentioning

confidence: 99%

Determination of antibiotics in meat samples using analytical methodologies: A review

Moga

Vergara-Barberán

Lerma‐García

et al. 2021

Comp Rev Food Sci Food Safe

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Antibiotics are widely used to prevent or treat some diseases in human and veterinary medicine and also as animal growth promoters. The presence of these compounds in foods derived from food‐producing animals can be a risk for human health. Consequently, regulatory agencies have set maximum residue limits for antibiotics in food samples. Therefore, the development of novel methodologies for its determination in food samples is required. Specifically, the analysis and quantification of these substances in meat tissues is a challenge for the analytical chemistry research community. This is due to the complexity of the matrix and the low detection limits required by the regulatory agencies. In this sense, a comprehensive review on the development of new sample preparation treatments involving extraction, cleanup, and enrichment steps of antibiotics in meat samples in combination with sensitive and sophisticated determination techniques that have been carry out in the last years is necessary. Therefore, the aim of this work is to summarize the published methodologies for the determination of antibiotics from 2016 until the beginning of the second semester of 2020. The first part of this review includes an introduction about antibiotic families, followed by sample preparation and determination techniques applied to the different families. Finally, a detailed discussion of the current trends and the future possible perspectives in this field are also included.

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Section: Quinolonesmentioning

confidence: 99%

Determination of antibiotics in meat samples using analytical methodologies: A review

Moga

Vergara-Barberán

Lerma‐García

et al. 2021

Comp Rev Food Sci Food Safe

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“…1 g of chitosan and 45 mL of ultra pure water were mixed and pH of the solution was adjusted to 3 with 1 mol Following this step, IL solution was added to chitosan solution and the mixture was stirred for 24 hours at room temperature. After that, the mixture was filtered and the sorbent was washed with dichloromethane and dried in a vacuum oven at~50-60 ºC [30]. Thus, the sorbent to be used for the sorption of uranium(VI) ions was prepared.…”

Section: Preparation Of Sorbentmentioning

confidence: 99%

Box–Behnken design for removal of uranium(VI) from aqueous solution using poly(ethylene glycol) based dicationic ionic liquid impregnated chitosan

İnan¹,

Mumcu²,

Bozkurt³

2020

Turk J Chem

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Poly(ethylene glycol) bis(methylimidazolium) di[bis(trifluoromethylsulfonyl)imide] was synthesized as an ionic liquid and impregnated onto chitosan. The removal of uranium(VI) ions from aqueous solution was investigated with batch sorption tests using ionic liquid impregnated chitosan. Response surface methodology based on 3 level Box-Behnken design was applied to analyze the effect of initial pH (4-6), initial concentration (20-60 mg L −1) , contact time (15-105 min), and temperature (30-50°C) on the uptake capacity of uranium(VI). Main effect of initial concentration, quadratic effect of contact time, and dual effect of initial pH and contact time were found statistically significant based on analysis of variance (ANOVA). Probability F-value (F = 1.49 ×10 −6) and correlation coefficient (R 2 = 0.96) point out that the proposed model is compatible with experimental data. The maximum uptake capacity of uranium(VI) was found as 28.48 mg g −1 at initial pH 4, initial concentration 60 mg L −1 , contact time of 70 min, and a temperature of 50°C. Sorption kinetics followed a pseudo-second-order model and Freundlich model was obtained to fit the sorption data. The presence of competing ions slightly reduced uranium(VI) sorption and the selectivity order can be given as UO 2+ 2 >Zn 2+ >Ni 2+ .

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“…Furthermore, a wide variety of novel materials have been employed to prepare efficient sorbents for the extraction of various analytes from fish samples. These include ionic liquids (ILs) and polymeric ILs [18], graphene [19], graphene oxide [20], carbon nanotubes [21], molecularly imprinted polymers [22] and metal-organic frameworks [23].…”

Section: Introductionmentioning

confidence: 99%

Novel Approaches Utilizing Metal-Organic Framework Composites for the Extraction of Organic Compounds and Metal Traces from Fish and Seafood

et al. 2020

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The determination of organic and inorganic pollutants in fish samples is a complex and demanding process, due to their high protein and fat content. Various novel sorbents including graphene, graphene oxide, molecular imprinted polymers, carbon nanotubes and metal-organic frameworks (MOFs) have been reported for the extraction and preconcentration of a wide range of contaminants from fish tissue. MOFs are crystalline porous materials that are composed of metal ions or clusters coordinated with organic linkers. Those materials exhibit extraordinary properties including high surface area, tunable pore size as well as good thermal and chemical stability. Therefore, metal-organic frameworks have been recently used in many fields of analytical chemistry including sample pretreatment, fabrication of stationary phases and chiral separations. Various MOFs, and especially their composites or hybrids, have been successfully utilized for the sample preparation of fish samples for the determination of organic (i.e., antibiotics, antimicrobial compounds, polycyclic aromatic hydrocarbons, etc.) and inorganic pollutants (i.e., mercury, palladium, cadmium, lead, etc.) as such or after functionalization with organic compounds.

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Use of ionic liquid based chitosan as sorbent for preconcentration of fluoroquinolones in milk, egg, fish, bovine, and chicken meat samples by solid phase extraction prior to HPLC determination

Cited by 26 publications

References 55 publications

Determination of antibiotics in meat samples using analytical methodologies: A review

Determination of antibiotics in meat samples using analytical methodologies: A review

Box–Behnken design for removal of uranium(VI) from aqueous solution using poly(ethylene glycol) based dicationic ionic liquid impregnated chitosan

Novel Approaches Utilizing Metal-Organic Framework Composites for the Extraction of Organic Compounds and Metal Traces from Fish and Seafood

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