Use of simple current-controlled coulometry in ultra-micro analysis

Buijsman, E; Krijgsman, W.; Oort, W. J. van; Osch, G. W. S. van; Hoekstra, I. W.; Griepink, B.

doi:10.1007/bf00445702

Z. Anal. Chem.

1974

DOI: 10.1007/bf00445702

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Use of simple current-controlled coulometry in ultra-micro analysis

E Buijsman

W. Krijgsman

W. J. van Oort

et al.

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1976

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“…Other developments are a simple constant-current source (206), a simple fluorescence detection system (165), and a small-scale cell for the external generation of coulometric titrants (18). Titration times of <10 s have been obtained in ultramicro determinations by controlled-current coulometry (47,274).…”

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Amperometric, bipotentiometric, and coulometric titrations

Stock¹

1976

Anal. Chem.

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The period covered by this survey is from the previous reviews (82, 342,343) through October, 1975. Unless otherwise specified, potentials are with respect to the saturated calomel electrode (SCE). In each area, the intended order of treatment is amperometric, bipotentiometric, and nonamperometric or coulometric. Many coulometric titrations are monitored amperometrically. When thus identified, they have been treated as amperometric titrations.Reviews of amperometric titrimetry include general aspects (326, 335), continuous analysis (185), nonaqueous systems (382), trace determinations (336), inorganic microanalysis (309), determination of antibiotics (364), measurements for industrial uses (253), determination of niobium (234), uses of 8-mercaptoquinoline (28), and of organic reagents in general (265). The value of polarized electrode titrimetry has been discussed (201). In addition to general aspects (31, 67, 142), reviews of coulometric titrimetry concern the electrogeneration of reagents (94), the titration of organic compounds (205), and continuous analysis (186,344,350).

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“…Primary-standard sulfamic acid has been assayed (389). The titration of 15-250 nanoequivalents of HC1 has been achieved in a few seconds (47). Sulfur in organic sulfur-halogen compounds has been determined by acidimetric titration of SO2 (108).…”

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Amperometric, bipotentiometric, and coulometric titrations

Stock¹

1976

Anal. Chem.

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Improvement of the determination of small amounts of chloride by coulometric titration

et al. 1977

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Some investigations for a titrimetric determination of nanomoles of carbon

Buijsman

Römer

Griepink

1977

Microchemical Journal

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Use of simple current-controlled coulometry in ultra-micro analysis

Cited by 4 publications

References 4 publications

Amperometric, bipotentiometric, and coulometric titrations

Amperometric, bipotentiometric, and coulometric titrations

Improvement of the determination of small amounts of chloride by coulometric titration

Some investigations for a titrimetric determination of nanomoles of carbon

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