This work is part of our research to develop facile green methods for synthesizing bioactive molecules from biomass. The current study deals with the preparation and investigation of the newly synthesized cyanoacetyl-acetylated microcrystalline cellulose (CAA-MCC). The novelty of this derivative lies not only in its ability to act as a green dry-film biocide/UV blocker for eco-friendly waterborne paints but also in being biomass-derived via solar pulping of rice straw, which is a mild process that produces cellulosic pulp and non-toxic black liquor. Solar acid dissociation of the bleached pulp produces microcrystalline cellulose (MCC), which was utilized to synthesize its acetate derivative incorporating the cyanoacetyl moiety (CAA-MCC). The presence of acetyl and cyano acetyl groups in CAA-MCC was confirmed using elemental and spectral analyses, including FT-IR and NMR. Two sets of paint formulations were prepared, one with CAA-MCC and the other with the commercial dry-film biocide Rocima 363. Scanning electron microscope (SEM) and energy-dispersive X-ray (EDAX) analyses were performed for MCC, CAA-MCC, and the prepared dry films. CAA-MCC demonstrated moderate antibacterial activity, encouraging its evaluation as a dry-film biocide and UV blocker. CAA-MCC paint films showed resistance to microbial growth on their surfaces without inhibition zones. Moreover, films were exposed to ultraviolet (UV) radiation while monitoring their color change over time. The results revealed that films containing CAA-MCC were more resistant to deterioration than those containing Rocima 363. Viscosity, X-cut adhesion, hardness, and water resistance were also evaluated, and they all improved with the CAA-MCC addition. CAA-MCC could act as a new, cost-effective alternative to petrochemical-derived biocides and UV blockers that can improve paint performance.
Graphical Abstract