“…Then, COO– reacts with the terminal amino group of the amino HBP to form a –CO–NH– group, and in this reaction, the white PAN fiber gradually changed into light yellow. Thus, the amino HBP was successfully grafted on the surface of PAN fibers [ 26 , 27 ]. Scheme 1 Preparation of PAN-G-HBP fiber …”
In this study, amino hyperbranched polymers (HBP)-grafted polyacrylonitrile (PAN) fiber was prepared through an amidation reaction in an autoclave. The prepared PAN-G-HBP fiber can complex Ag+ through amino groups of amino HBP, and in a hot steaming condition, Ag+ can be converted to Ag0 through the reducibility of HBP. PAN-G-HBP and Ag nanoparticles (NPs)-coated fibers were then characterized through FTIR, UV–VIS DRS, FE-SEM, EDS, XPS and antibacterial measurement. FTIR results confirmed HBP was grafted on the surface of PAN fiber. FE-SEM showed that after grafting with HBP, the average diameter of PAN fibers was amplified. EDS, XPS, and UV–VIS DRS method indicated that under hot steaming condition and with the reducibility of HBP, Ag NPs uniform coating on the PAN-G-HBP. Ag NPs-coated fibers exhibits excellent antibacterial property against Escherichia coli and Staphylococcus aureus. Even under 20 times home washing conditions, the antibacterial reduction of Ag NPs-coated PAN fiber can achieved more than 98.94%.
“…Then, COO– reacts with the terminal amino group of the amino HBP to form a –CO–NH– group, and in this reaction, the white PAN fiber gradually changed into light yellow. Thus, the amino HBP was successfully grafted on the surface of PAN fibers [ 26 , 27 ]. Scheme 1 Preparation of PAN-G-HBP fiber …”
In this study, amino hyperbranched polymers (HBP)-grafted polyacrylonitrile (PAN) fiber was prepared through an amidation reaction in an autoclave. The prepared PAN-G-HBP fiber can complex Ag+ through amino groups of amino HBP, and in a hot steaming condition, Ag+ can be converted to Ag0 through the reducibility of HBP. PAN-G-HBP and Ag nanoparticles (NPs)-coated fibers were then characterized through FTIR, UV–VIS DRS, FE-SEM, EDS, XPS and antibacterial measurement. FTIR results confirmed HBP was grafted on the surface of PAN fiber. FE-SEM showed that after grafting with HBP, the average diameter of PAN fibers was amplified. EDS, XPS, and UV–VIS DRS method indicated that under hot steaming condition and with the reducibility of HBP, Ag NPs uniform coating on the PAN-G-HBP. Ag NPs-coated fibers exhibits excellent antibacterial property against Escherichia coli and Staphylococcus aureus. Even under 20 times home washing conditions, the antibacterial reduction of Ag NPs-coated PAN fiber can achieved more than 98.94%.
“…For the regeneration of fibrous ion exchangers, a less regenerating solution is required in comparison with granular ion exchangers (Kopylova et al, 2006). In this regard, fibers are widely used both for wastewater treatment from various ions (Xu et al, 2021;Grachek et al, 2020;Wang et al, 2020) and for the recovery of rare earth elements (Li et al, 2020).…”
Background: Wastewater from the mineral fertilizer production, agribusiness containing ammonium ions causes significant harm to fish farming; therefore, it must be purified before discharge. Ion-exchange sorption is a promising method for isolating ammonium cations. The object of the study was a chemisorption fiber VION KN-1, which has developed surface and high sorption rate. Purpose: To study the sorption kinetics of ammonium cations from aqueous solutions on VION KN-1; to train an ANN to predict the degree of recovery of ammonium ions from wastewater using Statistica Neural Networks Version 13. Methods: The ammonium ion concentration in the solution was established by direct potentiometry. Sorption isotherms were constructed using the method of variable concentrations. To determine the limiting stage, the obtained kinetic dependencies were represented in the coordinates of the Boyd-Adamson equations for internal/external diffusion. Results and Discussion: During sorption from solutions with different ammonium nitrogen contents, the values of distribution coefficients (Kd) are at the level of 2.3ꞏ103 cm3/g, which significantly exceeds this parameter for granular ionites. Experimental sorption data were verified using Freundlich (R2 = 0.9224) and Langmuir (R2 = 0.9996) isotherms. The maximum degree of recovery (over 96 %) was achieved by passing a solution with a concentration of 11.3 mmol/dm3. Using an array of experimental data, the MLP-3-5-1 neural network was trained. The coefficient of determination R2 = 0.999420 obtained for the training sample characterizes high network performance. Conclusions: The Langmuir equation better describes the process of NH4+ sorption on a fibrous sorbent. It is reasonable to use VION KN-1 at the fine treatment stage. Ammonium ion desorption from the fiber was performed by acid solution. The resulting solutions of ammonium salts can be used as liquid fertilizers. The trained neural networks can be used to predict the degree of recovery of ammonium ions by sorbent VION KN-1.
“…32,33 In recent years, several workers have used polyacrylonitrile fibers as carriers to prepare new adsorbents. 30,34,35 In our previous work, we also focused on designing and synthesizing dipyridine, 36 aminophosphonic acid, 37 quaternary ammonium salt, 38 and chelated iron 39 functionalized fibers for removal of heavy metal ions and phosphate. For example, phosphate adsorption via iron loaded aminated polyacrylonitrile fibers reached an equilibrium value (24.14 mg P g −1 ) after 5 min.…”
The enrichment and separation of phosphorus-containing compounds from wastewater can prevent eutrophication and recycle non-renewable resource. Herein, we developed a recyclable functionalized polyacrylonitrile fiber (PANAF-Cl) capable of loading ionic liquid...
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