Abstract. The volatilization of ammonia (NH3) from fertilizer application and livestock wastes is an overwhelmingly important pathway of nitrogen losses
in agricultural ecosystems and constitutes the largest source of atmospheric
NH3. The volatilization of NH3 highly depends on environmental and
meteorological conditions, however, this phenomenon is poorly described in
current emission inventory and atmospheric models. Here, we develop a
dynamic NH3 emission model capable of calculating the NH3 emission
rate interactively with temporal- and spatial-varying meteorological and soil
conditions. The NH3 flux parameterization relies on several
meteorological factors and anthropogenic activity including fertilizer
application, livestock waste, traffic, residential, and industrial sectors.
The model is then embedded into a regional WRF–Chem model and is evaluated
against field measurements of NH3 concentrations, emission flux, and
satellite retrievals of column loading. The evaluation shows a substantial
improvement in the model performance of NH3 flux and ambient
concentration in China. The model represents the spatial and temporal
variations of ambient NH3 concentration well, indicating the highest
emission in the North China Plain (NCP) and Sichuan Basin, especially during
summertime. Compared with normal simulations using fixed emission inventory
input, this model features superior capability in simulating NH3
emission flux and concentration during drastic weather changes like frontal
activities and precipitation. Such advances in emission quantification also
improve the model performance of secondary inorganic aerosol on synoptic
scales. While more laboratory and field measurements are still needed for
better parameterization of NH3 volatilization, the seamless coupling of
soil emission with meteorology provides a better understanding of NH3
emission evolution and its contribution to atmospheric chemistry.