Utilization of Moringa oleifera seeds as a biosorbent for diclofenac removal in the contaminated aquatic systems

Abstract

During recent years, pharmaceuticals and their metabolites have been increasingly found in water bodies and diclofenac is one of the pharmaceuticals residues most frequently detected thus far. The aim of this work was to evaluate the Moringa oleifera seeds as an alternative for diclofenac (DCF) removal in water samples. The batch procedure for diclofenac removal at the optimized conditions (25 mL of 10.0 mg L−1 DCF, pH 5.0, extraction time of 30 min and M. oleifera mass of 2.0 grams) achieved adsorption of 100% of diclofenac in real water samples. The pseudo-second order kinetic described the adsorption rate-controlling step. The adsorption isotherms were fitted by Langmuir, Freundlich and Sips models and the sorption capacity of the biosorbent is spontaneously favourable. The maximum adsorptive capacity was estimated at 32.05 mg g−1 and 32.85 mg g−1 by Langmuir and Sips models, respectively. The advantages of this procedure include good reproducibility in the removal of DFC even at low concentrations in real samples and does not require an additional step of pre-treatment of the adsorbent. The results highlight the potential of Moringa oleifera seeds as a cheap, environmentally friendly alternative for the removal of diclofenac (DFC) from polluted water.

A review on the current approach for the sustainable production of nanocomposites from agricultural wastes and their application for the adsorption of organophosphate flame retardants

“…These include agro-industrial by-products, such as date stone, wood shavings and barks, coconut shells and fibres, bagasse, rice husk, corn stillage, fruit peels, fruit seeds, plant stalks, oil palm front etc. [60][61][62][63] Large volume of unprocessed wastes that are often discarded by the agricultural and industrial sectors can contaminate and harm the ecosystem. The improper treatment of these wastes before disposal may result in similar issues.…”