Utilization of modified silk cotton hull waste as an adsorbent for the removal of textile dye (reactive blue MR) from aqueous solution

Thangamani, K.; Sathishkumar, M.; Yousuf, Sameena; Vennilamani, N.; Kadirvelu, K.; Pattabhi, S.; Yun, Soon‐Il

doi:10.1016/j.biortech.2006.05.010

Cited by 58 publications

(36 citation statements)

References 15 publications

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“…Above pH 4.0, the removal of dyes studied remained almost constant until pH 10.0. Similar results were reported by several researchers for the adsorption of reactive dyes [6,36]. At higher pH levels, excess OH -ions compete with dye anions for biosorption sites on the adsorbent surface, resulting in less biosorption.…”

Section: Effect Of Phsupporting

confidence: 87%

Experimental and Isothermal Studies on Sorption of Congo Red by Modified Mycelial Biomass of Wood‐rotting Fungus

Binupriya

Sathishkumar²,

Kavitha

et al. 2007

CLEAN Soil Air Water

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Experimental and Isothermal Studies on Sorption of Congo Red by Modified Mycelial Biomass of Woodrotting FungusBatch biosorption experiments were carried out for the removal of Congo red from aqueous solution using native and pretreated mycelial pellets/biomass of Trametes versicolor. The effect of process parameters such as contact time, dye concentration, and pH on the extent of Congo red biosorption has been investigated. Higher dye concentrations resulted in lower biosorption. Increases in biomass dosage led to increases in the levels of biosorption. Biosorption kinetics and equilibrium data are essential basic requirements to develop an effective and accurate design model for the removal of the dye. A kinetic study showed that the biosorption of the dye on fungal biomass was a gradual process. Pseudo-first-order, pseudo-second-order, and Bangham's model were used to fit the experimental data. The results of the kinetic studies showed that the second-order kinetic model fitted well for the present experimental data. Equilibrium isotherms were analyzed by Langmuir, Freundlich, Dubnin-Radushkevich, and Temkin isotherms. The biosorption equilibrium data obeyed the Langmuir and Temkin isotherms well. Acidic pH was favorable for the biosorption of the dye. Studies on the pH effect and desorption show that chemisorption seems to play a major role in the biosorption process. Among the native and pretreated biomass studied, autoclaved biomass showed a better biosorption capacity.

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Section: Effect Of Phsupporting

confidence: 87%

Experimental and Isothermal Studies on Sorption of Congo Red by Modified Mycelial Biomass of Wood‐rotting Fungus

Binupriya

Sathishkumar²,

Kavitha

et al. 2007

CLEAN Soil Air Water

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“…At pH values above the pKa, the overall charge of the carbon surface is negative, which results in decreased PR adsorption. Higher adsorption of reactive dyes such as PR at pH 2 has also been reported by other authors [1,2,5,17,24]. It is known that the surface charge depends on the solution pH and the surface characteristics of the carbon.…”

Section: Effect Of Ph On Pr Adsorptionmentioning

confidence: 58%

“…Carbon activation by sulfuric acid causes corrosion of the surface introducing micro-, macro-and meso-pores [17]. Corrosion results in pore formation, which in turn increases the surface area.…”

Section: Sem and Microscopic Analysismentioning

confidence: 99%

“…The seeds were washed with water many times to remove fibrous substances and pigments and dried in a convection oven at 608C for 24 h. The dried seeds were boiled in 0.1 M H 2 SO 4 for 1 h to remove the remaining fibers adhering on the surface since they will increase the ash content if carbon is produced directly. The seeds were then thoroughly washed with distilled water until the pH of the spent solution was near the neutral range (6.8 -7.2) and dried in a convection oven at 608C for 24 h. Carbon was prepared by mixing one part of dried seeds with one part of concentrated H2SO4 (w/v) and holding the mixture at room temperature (30 l 28C) overnight [17]. The carbonized material was then washed with distilled water to remove free acid and soaked in 2% NaHCO3 overnight to remove any residual acid from the pores of the carbon.…”

Section: Preparation and Sem Analysis Of Adsorbentmentioning

confidence: 99%

“…Many microorganisms including bacteria and fungi are also reported to adsorb dyes [7] but they are not economically viable. Many cheap, easily available agricultural and/or plant-based materials, e. g., maize cob [8], jute fiber [9], pistachio shells [10], palm kernel shell [11], date pits [12], rice husk [13], mango seed kernel powder [14], plum kernels [15], olive stones [16], silk cotton hull [17], and kohlrabi peel [18] have been applied as adsorbent sources for the removal of the textile dyes from wastewater. Rubus coreanus Miq.…”

Section: Introductionmentioning

confidence: 99%

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Bokbunja Wine Industry Waste as Precursor Material for Carbonization and Its Utilization for the Removal of Procion Red MX‐5B from Aqueous Solutions

Binupriya

Sathishkumar

Jung

et al. 2008

CLEAN Soil Air Water

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Bokbunja (wild raspberry) seed waste from the Bokbunja wine industry is a serious environmental problem due to the increasing popularity of Bokbunja wines in recent years. In the present study, Bokbunja seeds were carbonized and used as an adsorbent for the removal of Procion Red MX-5B. A batch of carbon was further treated with nhexane to remove excess seed oil and used separately as an adsorbent for comparison. There was a slight variation in the adsorption capacities of n-hexane untreated (HUTC) and n-hexane treated carbon (HTC). The adsorption capacities predicted by the Langmuir isotherm were 29.37 and 30.65 mg/g for HUTC and HTC, respectively. The adsorption was found to be dependant on initial pH, contact time and initial dye concentration. The dye removal rates were higher at pH 2, while equilibrium time was achieved at 120 min. Kinetic studies showed a pseudo-first-order rate of adsorption. The results show that Bokbunja carbon could be used as a potential adsorbent for dye removal from wastewaters.

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The Use of Ultrasound in pipette‐tip solid‐phase extraction based on CuS@ZnS@Fe₃O₄‐CNTs for pre‐concentration of tartrazine in water samples

Ostovan

Asadollahzadeh

Ghaedi

2018

Applied Organom Chemis

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This paper report a novel strategy for synthesis and application of CuS@ZnS@Fe 3 O 4 -CNTs composite which has great potentials as artificial receptor for tartrazine trapping due to its ultrahigh surface area and functionality which is related to application of electrochemical route. A durable and economical pipette-tip CuS@ZnS@Fe 3 O 4 -CNTs nano-composite miniaturized solid phase extraction coupled with UV-Vis spectrophotometry was developed for clean-up and determination of tartrazine from various water samples. Undoubtedly, presence of mild-intensity/frequency ultrasound irradiation played a key role for reducing consumption of eluent volume by broking hydrogen bonds between retained analyte and sorbent. The influence of factors including pH, sorbent dosage, sonication time and eluent volume were investigated and optimum conditions were obtained using experimental design methodology. Under optimized conditions, good extraction efficiencies for the analyte were obtained with no matrix interference in the subsequent UV-Vis. Good linearity for tartrazine in the range of 20-5000 ng mL -1 with correlation coefficients of R 2 ≥ 0.99 and low detection limit close to 4.76 ng mL -1 reveals high applicability of method for trace analysis.

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Utilization of modified silk cotton hull waste as an adsorbent for the removal of textile dye (reactive blue MR) from aqueous solution

Cited by 58 publications

References 15 publications

Experimental and Isothermal Studies on Sorption of Congo Red by Modified Mycelial Biomass of Wood‐rotting Fungus

Experimental and Isothermal Studies on Sorption of Congo Red by Modified Mycelial Biomass of Wood‐rotting Fungus

Bokbunja Wine Industry Waste as Precursor Material for Carbonization and Its Utilization for the Removal of Procion Red MX‐5B from Aqueous Solutions

The Use of Ultrasound in pipette‐tip solid‐phase extraction based on CuS@ZnS@Fe₃O₄‐CNTs for pre‐concentration of tartrazine in water samples

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Utilization of modified silk cotton hull waste as an adsorbent for the removal of textile dye (reactive blue MR) from aqueous solution

Cited by 58 publications

References 15 publications

Experimental and Isothermal Studies on Sorption of Congo Red by Modified Mycelial Biomass of Wood‐rotting Fungus

Experimental and Isothermal Studies on Sorption of Congo Red by Modified Mycelial Biomass of Wood‐rotting Fungus

Bokbunja Wine Industry Waste as Precursor Material for Carbonization and Its Utilization for the Removal of Procion Red MX‐5B from Aqueous Solutions

The Use of Ultrasound in pipette‐tip solid‐phase extraction based on CuS@ZnS@Fe3O4‐CNTs for pre‐concentration of tartrazine in water samples

Contact Info

Product

Resources

About

The Use of Ultrasound in pipette‐tip solid‐phase extraction based on CuS@ZnS@Fe₃O₄‐CNTs for pre‐concentration of tartrazine in water samples