In industry, the refractory materials, generally resistant to high temperatures (>1500°C), are considered of great importance for thermal insulation and for the manufacture of furnaces. Fired bricks or unshaped materials (monolithic materials) are usually used for applications involving high temperatures in corrosive conditions (such as the presence of oxidizing or reducing agents), including the ceramic industry, iron and steel industry, non-ferrous metallurgy, petrochemical, cement and glass industry, incinerators, and energy production. The new feature requirements taking into consideration the working environments for better performance and lower production cost of the raw materials, are considered the main focus of numerous recent studies. The essential category of traditional refractory products is fireclay, with a high content of Alumina and Silica. The choice of material for traditional refractory and advanced materials' applications has been carried out based on the optimization between cost, quality and performance taking into consideration the working environments. Kaolin, the basic raw material for the production of Silica-Alumina refractories, is derived from the hydrothermal alteration of alkaline Granite which causes the kaolinization of alkali-feldspar of Granite rock and produces a friable aluminous material 1 : Feldspar Kaolin. This research work contributes to the development of local natural resources and to prospect the potentialities of 6SiO 2 2 O 3 K 2 O + 2H 2 O + CO 2 → 2SiO 2 2 O 3 2H 2 O + 4SiO 2 + K 2 CO 3