“…We analyse four NA simulants, namely trimethyl phosphate (TMP, Sigma-Aldrich, >99%), dimethyl methylphosphonate (DMMP, Fluka, 97%), diethyl methylphosphonate (DEMP, Sigma-Aldrich, 97.3%) and diisopropyl methylphosphonate (DIMP, Alfa Aesar, 95%), whose molecular structures and thus spectral properties are similar to G-series NAs such as sarin, tabun and soman (Ruiz-Pesante et al, 2007;Mott and Rez, 2012;Neupane et al, 2019;Kumar et al, 2019). Simulant samples in the gas phase are prepared by placing 20 μl of liquid simulant at the bottom of a one-liter container as illustrated at the bottom-right corner in Fig.…”