Over
the past few years, there has been a huge demand for developing
sensors capable of monitoring and quantifying volatiles related to
food quality analysis, medical diagnosis, and environmental monitoring.
Sensors designed for such applications are required to present simultaneously
high selectivity, low power consumption, fast response/recovery rate,
low humidity dependence, and
a low detection limit, which pose great challenges to be overcome
in the development of suitable transducer nanomaterials for gas sensing.
The nanostructure dimensionality certainly plays a key role for efficient
gas detection. Thanks to the advantages derived from the nanoscaled
size and the large surface-to-volume ratio, electrospun ceramic nanofibers
(ECNs) have demonstrated great potential for the design of gas-sensing
devices during the most recent years. Recently, studies have shown
that the sensitivity, selectivity, and other important sensing parameters
of ceramic nanofibers can be improved by designing heterojunctions
at the nanoscale. As a consequence, outstanding composite and hybrid
materials with unprecedented features have been recently reported
for the detection of hazardous gases. In view of the importance and
the potential impact of these results, here we review the latest findings
and progress reported in the literature on the factors that influence
the gas-sensing characteristics, as well as their application as gas
sensors for monitoring various volatiles. This review will help researchers
and engineers to understand the recent evolution and the challenges
related to electrospun ceramic-based gas sensors and also further
stimulate interest in the development of new gas-sensing devices.