2008
DOI: 10.1016/j.cej.2007.05.018
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UV-induced decolourization of acid alizarine violet N by homogeneous advanced oxidation processes

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Cited by 14 publications
(5 citation statements)
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“…However, generation of a non-selective and powerful oxidant, • OH radicals [28,29] by direct photolysis of added hydrogen peroxide (H 2 O 2 + h → 2 • OH) significantly enhanced the degradation of the dye, since complete decolorization (dye + • OH → products) was obtained in less than Because of the low molar absorptivity of H 2 O 2 at 254 nm (18.6-19.6 l/mol cm) [30], theoretically an excess of H 2 O 2 is needed to produce more • OH radicals. However in our previous work [31], in addition to other reports [32,33], we observed that the concentration of H 2 O 2 may either enhance or inhibit the photoreaction rate depending on concentration. Therefore an optimum concentration of H 2 O 2 in the reaction course must be reached.…”
Section: Effect Of H 2 Omentioning
confidence: 37%
“…However, generation of a non-selective and powerful oxidant, • OH radicals [28,29] by direct photolysis of added hydrogen peroxide (H 2 O 2 + h → 2 • OH) significantly enhanced the degradation of the dye, since complete decolorization (dye + • OH → products) was obtained in less than Because of the low molar absorptivity of H 2 O 2 at 254 nm (18.6-19.6 l/mol cm) [30], theoretically an excess of H 2 O 2 is needed to produce more • OH radicals. However in our previous work [31], in addition to other reports [32,33], we observed that the concentration of H 2 O 2 may either enhance or inhibit the photoreaction rate depending on concentration. Therefore an optimum concentration of H 2 O 2 in the reaction course must be reached.…”
Section: Effect Of H 2 Omentioning
confidence: 37%
“…They preferentially disproportionate and produce hydrogen peroxide and dioxygen (reaction (20)): On the other hand, several authors have reported that the peroxide self-decomposition rate, which is strongly pH dependent, partly contributes to the decrease of the k app values in alkaline medium (reaction (21)): 27,35 2 They preferentially disproportionate and produce hydrogen peroxide and dioxygen (reaction (20)): On the other hand, several authors have reported that the peroxide self-decomposition rate, which is strongly pH dependent, partly contributes to the decrease of the k app values in alkaline medium (reaction (21)): 27,35 2…”
Section: The Effect Of the Initial H 2 O 2 Concentrationmentioning
confidence: 99%
“…NZVI alone in the absence of H 2 O 2 was found to have no obvious effect on the decolorization of the dye. According to some reports [10,11], the concentration of H 2 O 2 may either enhance or inhibit the degradation rate. Therefore, an optimum concentration of H 2 O 2 in AFP must be reached.…”
Section: Resultsmentioning
confidence: 99%