V‐MXenes for Energy Storage/Conversion Applications

Hussain, Iftikhar; Kewate, Onkar Jaywant; Hanan, Abdul; Bibi, Faiza; Javed, Muhammad Sufyan; Rosaiah, P.; Ahmad, Muhammad; Chen, Xi; Shaheen, Irum; Hanif, Muhammad Bilal; Bhatti, Ali Hassan; Assiri, Mohammed Ali; Zoubi, Wail Al; Zhang, Kaili

doi:10.1002/cssc.202400283

ChemSusChem

2024

DOI: 10.1002/cssc.202400283

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V‐MXenes for Energy Storage/Conversion Applications

Iftikhar Hussain,

Onkar Jaywant Kewate,

Abdul Hanan

et al.

Abstract: MXenes, a two‐dimensional (2D) material, exhibit excellent optical, electrical, chemical, mechanical, and electrochemical properties. Titanium‐based MXene (Ti‐MXene) has been extensively studied and serves as the foundation for 2D MXenes. However, other transition metals possess the potential to offer excellent properties in various applications. This comprehensive review aims to provide an overview of the properties, challenges, key findings, and applications of less‐explored vanadium‐based MXenes (V‐MXenes) … Show more

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Cited by 12 publications

References 183 publications

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Non‐Ti (M₂X and M₃X₂) MXenes for Energy Storage/Conversion

Hussain,

Hanan,

Bibi

et al. 2024

Advanced Energy Materials

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MXenes, with a particular emphasis on Ti3C2 (M3X2) have been extensively studied and established as the foundational material for 2D MXenes. However, the exploration of other transitional metals as 2D MXenes holds great promise, offering applications beyond the existing knowledge. Non‐Ti (M2X and M3X2) MXenes have garnered attention due to their distinctive properties. This review article focuses on explaining the potential and challenges of non‐Ti (M2X and M3X2) MXenes in energy storage and conversion systems, specifically in the domains of supercapacitors, batteries (Li‐ion and Li‐S), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR). By providing a comprehensive overview of the current progress and addressing the associated challenges, this review offers valuable insights into the future prospects of not only non‐Ti (M2X and M3X2) MXenes but also other MXenes for energy storage and conversion. The findings presented herein pave the way for further research and multifaceted applications of these MXenes across various fields.

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Non‐Ti (M₂X and M₃X₂) MXenes for Energy Storage/Conversion

Hussain,

Hanan,

Bibi

et al. 2024

Advanced Energy Materials

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Double transition metal MXenes for enhanced electrochemical applications: Challenges and opportunities

Bibi,

Hanan,

Soomro

et al. 2024

EcoMat

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Double transition metal (DTM) MXenes are a recently discovered class of two‐dimensional composite nanomaterials with excellent potential in energy storage applications. Since their emergence in 2015, DTM MXenes have expanded their composition boundary beyond traditional single‐metal carbide and nitride MXenes. DTM MXenes offer tunable structures and properties through variations in the constituent transition metals and positioning within the layered lattice. These MXenes can exist in two primary forms: ordered DTMs and solid solutions. The compositional versatility of DTM MXenes offers opportunities to enhance their performance in electrochemical energy storage applications. However, the quality, stability, and surface chemistry of DTM MXenes are influenced by several factors, including the etching process, etchant type, and synthesis route. Currently, limited literature is available on experimentally synthesized DTM MXenes, with most studies focusing on carbide‐based MXenes. Most of the articles have dedicated their efforts only to generalized synthesis strategies. Although extensive theoretical studies have explored the suitability of etchants, synthesis parameters, and methods for producing high‐quality MXene with selective terminal functional groups, their stability issues have not been thoroughly examined. This review addresses various types of DTM MXenes, their synthesis techniques, and the impact of these methods on their physicochemical properties and electrochemical performance. Additionally, it provides a critical analysis of the causes of instability in MXenes, particularly DTMs, from synthesis to application. The challenges associated with these materials are discussed, along with opportunities and prospects for enhancing synthesis, structural tuning, surface modification, and applications in electrochemical energy storage.image

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Recent Advances in Potential Biomedical Applications of MXene‐Based Hydrogels

Hamzehlouy,

Tavakoli Dare,

Shahi

et al. 2024

Polymers for Advanced Techs

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MXene‐based hydrogels represent a significant advancement in biomedical material science, leveraging the unique properties of 2D MXenes and the versatile functionality of hydrogels. This review discusses recent developments in the integration of MXenes into hydrogel matrices, focusing on their biomedical applications such as wound healing, drug delivery, antimicrobial activity, tissue engineering, and biosensing. MXenes, due to their remarkable electrical conductivity, mechanical robustness, and tunable surface chemistry, enhance the mechanical properties, conductivity, and responsiveness of hydrogels to environmental stimuli. Specifically, MXene‐based hydrogels have shown great promise in accelerating wound healing through photothermal effects, delivering drugs in a controlled manner, and serving as antibacterial agents. Their integration into hydrogels also enables applications in targeted cancer therapies, including photothermal and chemodynamic therapies, facilitated by their high conductivity and tunable properties. Despite the promising progress, challenges such as ensuring biocompatibility and optimizing the synthesis for large‐scale production remain. This review aims to provide a comprehensive overview of the current state of MXene‐based hydrogels in biomedical applications, highlighting the ongoing advancements and potential future directions for these multifunctional materials.

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V‐MXenes for Energy Storage/Conversion Applications

Cited by 12 publications

References 183 publications

Non‐Ti (M₂X and M₃X₂) MXenes for Energy Storage/Conversion

Non‐Ti (M₂X and M₃X₂) MXenes for Energy Storage/Conversion

Double transition metal MXenes for enhanced electrochemical applications: Challenges and opportunities

Recent Advances in Potential Biomedical Applications of MXene‐Based Hydrogels

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V‐MXenes for Energy Storage/Conversion Applications

Cited by 12 publications

References 183 publications

Non‐Ti (M2X and M3X2) MXenes for Energy Storage/Conversion

Non‐Ti (M2X and M3X2) MXenes for Energy Storage/Conversion

Double transition metal MXenes for enhanced electrochemical applications: Challenges and opportunities

Recent Advances in Potential Biomedical Applications of MXene‐Based Hydrogels

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Product

Resources

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Non‐Ti (M₂X and M₃X₂) MXenes for Energy Storage/Conversion

Non‐Ti (M₂X and M₃X₂) MXenes for Energy Storage/Conversion