Vanadium doped gallium lanthanum sulphide glass ͑V:GLS͒ displays three absorption bands at 580, 730, and 1155 nm identified by photoluminescence excitation measurements. Broad photoluminescence, with a full width at half maximum of ϳ500 nm, is observed peaking at 1500 nm when exciting at 514, 808, and 1064 nm. The fluorescence lifetime and quantum efficiency at 300 K were measured to be 33.4 s and 4%, respectively. From the available spectroscopic data, the authors propose the vanadium ions' valence to be 3+ and be in tetrahedral coordination. Chalcogenide glasses have low phonon energies due to the relatively large atomic mass of their constituent atoms. In particular, gallium lanthanum sulphide ͑GLS͒ glass has a maximum phonon energy of 425 cm −1 , which gives it excellent infrared transmission up to 9 m. 1 This low maximum phonon energy enables emission from many transitions within active ion dopants, such as transition metals, which are weakly or not at all observed in other glasses ͑e.g., silica͒ due to their high phonon energies. In this letter we present spectroscopic data for vanadium doped GLS ͑V:GLS͒ glass. We assign a 3+ oxidation state to the vanadium ion and energy levels to the observed transitions by comparisons to previous work on the spectroscopic analysis of V 3+ in other hosts.Samples of V:GLS were prepared by mixing 65% gallium sulphide ͑Ga x S y ͒, 29.95% lanthanum sulphide ͑La 2 S 3 ͒, 5% lanthanum oxide ͑La 2 O 3 ͒, and 0.05% vanadium sulphide ͑V 2 S 3 ͒ ͑mol %͒ in a dry-nitrogen purged glovebox. Gallium and lanthanum sulphides were synthesized in-house from gallium metal ͑9N purity͒ and lanthanum fluoride ͑5N purity͒ precursors in a flowing H 2 S gas system. Before sulphurization, lanthanum fluoride was purified and dehydrated in a dry-argon purged furnace at 1250°C for 36 h to reduce OH − and transition metal impurities. The lanthanum oxide and vanadium sulphide were purchased commercially and used without further purification. The glass was melted in a dryargon purged furnace at 1150°C for 24 h before being quenched and annealed at 400°C for 12 h.Absorption spectra were taken on a Varian Cary 500 spectrophotometer over a range of 175-3300 nm with a resolution of ±0.1 nm. Samples were cut and polished into 5 and 0.5 mm thick slabs, which allowed reflection corrected absorption coefficient spectra to be calculated using.