Aqueous supercapacitors (SCs) exhibit several advantages, including high-power density, cycling durability, and safety; however, the shortage of low energy density inhibits their further application. Acquiring an excellent performance upon using simple strategies would be beneficial, but remains challenging. Here, an integrated electrode of hollow V 2 O 3 /carbon nanospheres (H-V 2 O 3 /C) was designed and synthesized for SCs. The introduction of carbon can increase the conductivity and stability, whereas the hollow structure endows H-V 2 O 3 /C with a high specific surface area and rapid transport of ions. Moreover, the H-V 2 O 3 /C integrated electrode can simultaneously work in both negative and positive potential windows. Benefiting from these advantages, the H-V 2 O 3 /C integrated electrode exhibits a specific capacitance as high as 708.6 F g −1 in a wide voltage window of −1.1-1.3 V. Furthermore, stemming from the multiple energy storage mechanisms, the aqueous integrated full SC device exhibits a wider potential window and higher energy density than the traditional (a)symmetric ones. Therefore, the proposed device delivers a wide voltage window of 2.4 V with an energy density of 96.8 W h kg −1 at a power density of 1204.6 W kg −1 , as well as superior cycling stability. This study enlightens the design and preparation of electrode materials, opening up a possible approach for developing wide-voltage aqueous SCs.