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Synthesis, characterization and biological activities of 3-methylbenzyl 2-(6-methyl pyridin-2-ylmethylene)hydrazine carbodithioate and its transition metal complexes

“…The molar conductance values of the complexes in DMSO (Table 1) fall in the range 5.45-12.11 X -1 cm 2 mol -1 , indicating that they are essentially non-electrolytes in DMSO. [3].…”

“…These compounds possess a wide range of biological activities which vary when the structure of the complex is slightly changed by the introduction or removal of different functional groups [1][2][3][4][5][6][7][8][9].…”

Synthesis, spectroscopic characterization, and 3D molecular modeling of lead(II) complexes of unsymmetrical tetradentate Schiff-base ligands

“…Infrared spectra in the region 4,000-400 cm -1 were recorded on a Perkin-Elmer RX1 FTIR spectrometer. 1 H NMR spectra were recorded on a Jeol (model FX 90Q) using DMSO-d 6 as solvent at 89.55 MHz. 13 C NMR spectra were recorded on a 90 MHz Jeol (FX 90Q) NMR spectrometer using dry DMSO as solvent at 84.25 MHz.…”

“…The Schiff base moiety is potentially ambidenate and can coordinate through nitrogen with either oxygen or sulfur atoms. The vast literature on structural studies of Schiff-base complexes reveals some interesting features of their coordination behavior [1][2][3][4][5][6][7][8].…”

[Fe(III)(salophen)]Cl in Molten Tetrabutylammonium Bromide as a New Homogeneous Catalytic System for the Electrophilic Reaction of Indole with Carbonyl Compounds

“…2 The complexes of diand trivalent transition metals involving derivatives of salicylaldehyde and aliphatic or aromatic amines are of immense importance because of their potential as catalyst for some catalytic reactions [3][4][5] and biological activities. [6][7][8] N,N'-Bis(salicylidene)-1,2-phenylenediamine (salophen), which is one of the most popular symmetrical tetradentate ligand, forms complexes with various metal ions and organic compounds. 9 The complexation reactions of this ligand in nonaqueous matrices could be used as an efficient strategy to design the analytical systems such as potentiometric sensors, [10][11][12] bulk liquid membrane transports, 13 optical sensors, 14 solid phase extraction 15 and biochemistry fields.…”