In this paper, arc thermal spray coating was conducted onto the SS400 steel using Inconel 625 wires in order to improve the durability of marine steel structures, and then investigated cavitation damage behavior of Inconel 625 coating layer in sea water. For the Inconel 625 coating layer, surface hardness appeared similar to that of existing high velocity oxy-fuel coating technology with 380~480 H V, but the porosity of about 6 % was larger relatively. During the cavitation experiment, pit damages were originated and grown at the rough surface and pore defect area of Inconel 625 coating layer. And, after the 72 hours of experimental time, weight loss of Inconel 625 coating layer exhibited gradually increasing tendency due to surface damage effect of the undercut.