Hydrogen energy has a series of advantages, such as high energy density, high utilization efficiency, good storage and transportation performance, zero pollution to the environment and so on. Hydrogen energy has a series of advantages, such as high energy density, high utilization efficiency, good storage and transportation performance, zero pollution to the environment and so on. With the help of renewable solar energy to provide heat, this hydrogen production process is expected to truly realize the sustainable development of energy. Its research has important strategic significance and social value. Firstly, the progress on hydrogen energy production based on solar biomass is summarized. Secondly, the consumption mechanism of hydrogen production from biomass driven by solar energy is analyzed. Thirdly, the preparation of Fe-Ce catalyst is designed. Finally, the hydrogen production effect based on different catalysts is analyzed, results show that Fe-Ce catalyst can effectively improve the quality of hydrogen production based on solar biomass.