Validation of an updated fractionation and indirect speciation procedure for inorganic arsenic in oxic and suboxic soils and sediments

Lock, Alan; Wallschläger, Dirk; McMurdo, Colin J.; Tyler, Laura Terry; Belzile, Nelson; Spiers, Graeme

doi:10.1016/j.envpol.2016.09.013

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Comparison Between the Two Extraction Schemes2

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“…However, it is reported that ammonium oxalate in acid medium is effective for extracting amorphous oxides/hydroxides of both Fe and Al. 9,10,28 In the absence of catalyzing effect of light, this reagent does not dissolve crystalline Fe oxides. 9,28 At the same time, the ascorbic acid/ammonium oxalate reagent adequate for dissolving crystalline Fe oxides and does not attack silicates.…”

Section: Comparison Between the Two Extraction Schemesmentioning

confidence: 98%

“…9,28 At the same time, the ascorbic acid/ammonium oxalate reagent adequate for dissolving crystalline Fe oxides and does not attack silicates. 9,10,28 Therefore, Wenzel SEP is likely to advantageous over the Tessier SEP to extract the reducible fraction of tungsten concentration associated with Fe/Al oxides/hydroxides.…”

Section: Comparison Between the Two Extraction Schemesmentioning

confidence: 99%

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