Pineapple is a widely cultivated, consumed, and processed fruit by the industry. However, only 22.5% of the whole fruit is used, which constitutes economic waste and environmental impact. The objective was to determine the drying kinetics and characterize the residual peel flours of two pineapple varieties at four drying temperatures. Jupi and Pérola pineapple peels were dried at temperatures of 50, 60, 70, and 80 °C in a thin layer. Ten mathematical models were adjusted to the experimental data to characterize the drying process. Fresh samples and flours were characterized according to their physicochemical properties (water content, ash, water activity, total sugars, reducers, pH, acidity, proteins, lipids, carbohydrates, and total energy value—TEV). The Midilli model was chosen because it best represents the drying process with high values of determination coefficients (R2) and low mean squared deviations (MSD), Chi-square (χ2), and estimated mean error (EME). The increase in temperature led to an increase in the effective diffusivity coefficient and consequent reduction in drying time. The activation energy obtained from the Arrhenius equation was 24.59 and 26.25 kJ/mol for Jupi and Pérola, respectively. Differences were reported in the enthalpy and entropy decrease with the increasing temperature, contrary to the Gibbs free energy. The flours produced had good characteristics for conservation, being acidic with low water content and low water activity. High levels of total and reducing sugars, carbohydrates, and total energy value were observed, in addition to good protein content.