Valorization of Different Clays Used in the Treatment of Oily Wastewater in the Development of Construction Products

Abstract

The aim of this research is to study the feasibility of using clays used in the decontamination of wastewater containing olive oil wastewater (OOW), new lubricating oil (NOW) or motor oil (MOW) in the manufacture of ceramic bricks. Three types of clays were used for filtration, kaolinite type clay (KT), smectite type clay (CT) both from Tunisia and illitic chloritic clay (CS) from Jaén (Spain). These clays containing different types of oils, as well as the control clays, were used in the manufacture of bricks fired at 900 °C. These bricks were characterized by physical, mechanical and thermal tests. The sintered microstructure’s evolution was followed by tracked through scanning electron microscopy (SEM) and X-ray diffraction analysis (XRD). The results indicate that the specific type of clay used influences the technological characteristics of the bricks. The use of CT clay gives rise to increase bulk density, greater compressive strength, and reduced apparent porosity and water absorption. The use of clays used in the decontamination of water containing oils produced a decrease in bulk density, compressive strength and thermal conductivity and leads to an increase in apparent porosity and water absorption in the order OOW > NOW > MOW according to the total organic carbon content (TOC). Therefore, the use of clays used in the filtration of water that contain different oils can represent a promising way of valorizing this waste, which can alleviate the environmental impact and represents economic savings for the industry of construction materials with properties of thermal insulation, getting closer to a circular economy.