Transactions are the most common phenomenon in market economy. But in theoretical research, modeling a transaction is a complex problem unsolved. In this paper, firstly, natural rationality (A) is defined as nonlinear function of agent's benefit (B) and cost(C), andThis mathematical model of natural rationality can be considered as one answer to Aumann's "open problem". Secondly, Three basic definitions of neutrality value system for market economy are constructed: commodity value, seller value and buyer value. Thirdly, value equilibrium of a bargaining game is modeled when the seller value is equal to the buyer value, and equilibrium price solution in a transaction is obtained. Finally, On these basis, the sequential bargaining process between two rationality agents (a seller and a buyer) is modeled in a time series by analytical geometry.