Vanadium Pentoxide as a Catalyst for Regioselective Nitration of Organic Compounds under Conventional and Nonconventional Conditions

Waste-Extracted Zn and Ag Co-Doped Spent Catalyst-Extracted V2O5 for Photocatalytic Degradation of Congo Red Dye: Effect of Metal-Nonmetal Co-Doping

“…In fact, several research papers have been published on the doping of transition metals to engineer their electrical and photocatalytic capabilities in photodegradation of organic pollutants [9,[11][12][13][14]. Vanadium pentoxide is an oxyanion of vanadium with a bandgap of 2.3 eV [15]. The photocatalytic activity of V 2 O 5 in powder form stimulates it as a viable prospect for the degradation of various organic molecules [16].…”

Trichloroisocyanuric acid (TCCA) and carboxamide interactions in TCCA/NaNO2 triggered nitration of pyrrole and indole in aqueous aprotic media: A kinetic correlation of solvent properties with reactivity

“…In several protocols, we have either completely avoided or minimized the use of mineral acids. [4][5][6][7][8][9][10] In 1902, Chattaway and Wadmore 11 reported the use of trichloroisocyanuric acid (TCCA) as a versatile oxidizing and chlorinating laboratory reagent, which is economically cheap, environmentally safe, less toxic, and easily available. 12 On the other hand, there has been an upsurge in the use of N,N′-dimethylformamide (DMF) by physical organic and organic chemists, because it is a polar aprotic solvent and exhibits hydrophilic properties.…”

“…Ours is one among the several research groups, which has undertaken the development of certain protocols to achieve nitration by replacing an acid mixture. In several protocols, we have either completely avoided or minimized the use of mineral acids 4–10 . In 1902, Chattaway and Wadmore 11 reported the use of trichloroisocyanuric acid (TCCA) as a versatile oxidizing and chlorinating laboratory reagent, which is economically cheap, environmentally safe, less toxic, and easily available 12 .…”

Kinetics and mechanism of trichloroisocyanuric acid/NaNO2‐triggered nitration of aromatic compounds under acid‐free and Vilsmeier‐Haack conditions

“…During the past five decades, quite a good number of nitrating regents have been developed to address the issues that are found in classical nitration procedure . During the past one decade, our group has also been actively working on the development of ecofriendly and cost‐effective nitrating agents and accomplished few noteworthy nitration protocols under acid‐free conditions . Trichloroisocyanuric acid (TCCA) is a cost‐effective, less toxic, less corrosive, efficient, and versatile laboratory reagent, which has been reported in 1902 by for the first time by Chattaway and Wadmore and explored as an efficient reagent for oxidation and chlorination reactions .…”

“…[3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19] During the past one decade, our group has also been actively working on the development of ecofriendly and cost-effective nitrating agents and accomplished few noteworthy nitration protocols under acid-free conditions. [20][21][22][23][24] Trichloroisocyanuric acid (TCCA) is a cost-effective, less toxic, less corrosive, efficient, and versatile laboratory reagent, which has been reported in 1902 by for the first time by Chattaway and Wadmore 25 and explored as an efficient reagent for oxidation and chlorination reactions. [26][27][28][29] Recently, we have reported the TCCA/N,N ′ -dimethyl formamide (DMF) is an efficient reagent for chlorodehydration of alcohols, 22 decarboxylative nitration of , -unsaturated carboxylic acids, and nitration of aromatic compounds using (TCCA-DMF)/NaNO 2 reagent in the presence of mineral acid-free conditions.…”