Vanadium–Titanium Magnetite Concentrate, Calcium–Magnesium Composite Roasting and Sulfuric Acid Leaching for Vanadium Extraction from Pellets

Abstract

This paper investigated a pellet ore production process in which vanadium was extracted from vanadium and titanium magnetite concentrates using sulfuric acid leaching. Calcium and magnesium were added to the iron ore concentrate during pellet production to produce calcium vanadate and magnesium vanadate after roasting. The pellets were leached with sulfuric acid solution to extract V5+. The resulting pellets had a compressive strength of 3375 N after primary roasting, a good pellet morphology after acid leaching, and simple liquid–solid separation. Under the optimal experimental conditions, the vanadium leaching rate in the pellets reached 77.86%, while the iron leaching rate was only 1.17%. The pellets did not fragment, which was an improvement upon existing vanadium extraction methods. The strength of the pellets after vanadium extraction decreased to 563 N, but after secondary roasting, the compressive strength of the pellets reached 2578 N, which was suitable for blast furnace ironmaking. The roasting and acid leaching experiments showed that the vanadium extraction process resulted in suitable pellet properties. The use of low compound additives can effectively improve the leaching effect, while avoiding the previous problems of too many additives, pellet iron grade reduction, or the pursuit of high vanadium extraction rate pellet breakage and serious high secondary use process costs.

Unveiling the bioleaching versatility of Acidithiobacillus ferrooxidans

“…Minerals conducive to V extraction encompass V-titanium magnetite ((V, Ti),Fe 2+ Fe 3+ 2 O 4 ), maghemite (a specific variant of magnetite characterized by a low Fe 2+ concentration), bixbyte (containing V along with (Mn, Fe) 2 O 3 )), V oxide, and jacobsite, typically (Mn, Mg)Fe 2 O 4 (Peng et al, 2023). A prominent participant in the interaction with these mineral types for V extraction is A. ferrooxidans, catalyzing the conversion of Fe 2+ to Fe 3+ under acidic conditions, as depicted below (Bredberg et al, 2004):…”