Flows of two-component mixtures with vapor condensation on cooled surfaces are analyzed by the methods of molecular-kinetic theory. The mixture contains a noncondensable component whose average density remains constant in the region under study. The influence of the gas on the process of recondensation of the vapor and the interaction of the components of the mixture in the cases of equal and different molecular weights are studied. The problems posed are investigated using the method of direct numerical solution of the kinetic Boltzmann equation modified for the mixture of gases. Special emphasis is placed on compution of direct and cross collision integrals.Problems in solving which one must take into account the nonequilibrium of transfer processes are topical for many situations of practical importance.In a number of practical applications, one frequently has such regimes of flow in which the regularities of flows of a continuous medium, on the one hand, and those of a free-molecular medium, on the other, cease to hold.Under such conditions, intermolecular collisions turn out to be insufficient for the superposition of a large number of random interactions to completely counterbalance their probabilistic character and to make it possible to use the regularities of a continuous medium. At the same time, collisions between gas or vapor particles are rather frequent and they cannot be disregarded, as in the case of a free-molecular regime of flow. Therefore, it is expedient to describe rarefied-gas flows at the level of the velocity-distribution function of molecules.The problem of calculation of the parameters of gas or vapor flows is also complicated by the presence of at least two components of the gas which interact with each other and by the phase transitions on cooled surfaces.Correct investigation of such flows is possible by the methods of molecular-kinetic theory. The motion and interaction of gas or vapor molecules are described based on the kinetic equation. In the present work, we use, as such an equation, the traditional Boltzmann equation, which, for a two-component mixture, becomes the system of equations ∂f a ∂t + ξ a ∂f a ∂r = J aa + J ab , ∂f b ∂t + ξ b ∂f b ∂r = J bb + J ba .In this work, we use collision integrals written in the following form: