Vapor–liquid equilibria of isopropyl alcohol+propylene at high pressures: Experimental measurement and modeling with the CPA EoS

Keshtkari, Simin; Haghbakhsh, Reza; Raeissi, Sona; Florusse, Louw J.; Peters, Cor J.

doi:10.1016/j.supflu.2013.09.016

Cited by 14 publications

(16 citation statements)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Among cubic equations, the Peng-Robinson and Soave-Redlich-Kowang equations of state are widely used for determining high-pressure phase equilibria (Stevens et al, 1997;Adrian et al, 1998;Liao et al, 2010;Hou et al, 2012;Brandalize et al, 2014;Machida et al, 2014;Pereira et al, 2014). In addition to the cubic equations of state, CPA and GC equations of state are also used to predict thermodynamic properties and high-pressure phase behavior of fluids (Espinosa et al, 2002;Fernández-Ronco et al, 2010;Keshtkari et al, 2013;Masoodiyeh et al, 2013).…”

Section: Vapor-liquid Equilibriummentioning

confidence: 99%

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Rad

Karimi-Sabet

Varaminian

2019

Braz. J. Chem. Eng.

View full text Add to dashboard Cite

Due to the importance of supercritical fluid technology (SFT) in different industries, it has been the subject of intense research in recent decades. Solubility is a key concept in SFT. In fact, obtaining knowledge about the theoretical concepts of solubility and related experimental measurement methods can be useful in developing and improving the quality of research in this field. This study reviews the fundamental knowledge of solubility in supercritical fluids and investigates the significant topics in this field, including high-pressure phase behavior, experimental measurement methods, modeling, and molecular simulation of solubility.

show abstract

Section: Vapor-liquid Equilibriummentioning

confidence: 99%

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Rad

Karimi-Sabet

Varaminian

2019

Braz. J. Chem. Eng.

View full text Add to dashboard Cite

show abstract

“…It is necessary to specify an association scheme, i.e., the type and number of association sites for each species in order to determine the value of X Ai for the associating components based on the association schemes proposed by Huang and Radosz [28,31,32].…”

Section: The Cubic Plus Association (Cpa) Equation Of Statementioning

confidence: 99%

“…Different studies in the literature have shown that the use of the 2B scheme is the simpler choice [31,32].…”

Section: The Cubic Plus Association (Cpa) Equation Of Statementioning

confidence: 99%

High pressure viscosity modeling of pure alcohols based on classical and advanced equations of state

Parvaneh

Haghbakhsh

Rahimpour

2016

Journal of the Taiwan Institute of Chemical Engineers

Self Cite

View full text Add to dashboard Cite

“…However, the non-ideal mixture of CO 2 + secondary butyl alcohol has not yet been modelled with the more complicated EoS which are particularly developed for associating systems, for example, the cubic-plus-association (CPA) or the different versions of the statistical association fluid theory (SAFT) [ 9 ]. CPA is among the more complicated EoS, developed on the basis of Wertheim’s theory.…”

Section: Introductionmentioning

confidence: 99%

“…Therefore, it can extend the capabilities of the cubic EoS to accurately model polar/hydrogen-bonding compounds. For example, in the oil and gas industries, it has the potential to incorporate hydrocarbons, gases, water, alcohols and glycols [ 9 – 13 ].…”

Section: Introductionmentioning

confidence: 99%

Solubility of Carbon Dioxide in Secondary Butyl Alcohol at High Pressures: Experimental and Modeling with CPA

et al. 2015

Self Cite

View full text Add to dashboard Cite

Mixtures of carbon dioxide and secondary butyl alcohol at high pressures are interesting for a range of industrial applications. Therefore, it is important to have trustworthy experimental data on the high-pressure phase behavior of this mixture over a wide range of temperatures. In addition, an accurate thermodynamic model is necessary for the optimal design and operation of processes. In this study, bubble points of binary mixtures of CO2 + secondary butyl alcohol were measured using a synthetic method. Measurements covered a CO2 molar concentration range of (0.10–0.57) % and temperatures from (293 to 370) K, with pressures reaching up to 11 MPa. The experimental data were modelled by the cubic plus association (CPA) equation of state (EoS), as well as the more simple Soave–Redlich–Kwong (SRK) EoS. Predictive and correlative modes were considered for both models. In the predictive mode, the CPA performs better than the SRK because it also considers associations.

show abstract

Vapor–liquid equilibria of isopropyl alcohol+propylene at high pressures: Experimental measurement and modeling with the CPA EoS

Cited by 14 publications

References 33 publications

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

Study of Solubility in Supercritical Fluids: Thermodynamic Concepts and Measurement Methods - A Review

High pressure viscosity modeling of pure alcohols based on classical and advanced equations of state

Solubility of Carbon Dioxide in Secondary Butyl Alcohol at High Pressures: Experimental and Modeling with CPA

Contact Info

Product

Resources

About