Vapor-liquid equilibrium data for the binary systems methanol-benzene and methyl acetate-methanol

Abstract

or by a direct fit independent of Equations 1 and 2, as **-[«&* H*"•' ,4' These correlations were made to provide empirical relations of the susceptibility as a function of concentration and temperature. The theoretical expressions (6) do not, for the most part, fit the experimental data within one to two orders of magnitude.

Vapor-Liquid Equilibrium Data for Methanol, Ethanol, Methyl Acetate, Ethyl Acetate, and o-Xylene at 101.3 kPa

“…The extra heater was designed to keep the upper zone at the same temperature as in the boiler. The operation of the apparatus was checked with methanol ± methyl acetate, and the results agree with those of Nagata (12) as can be seen in Figures were connected, and the mixture reached the boiling point and was kept there for 120 min, to ensure that a steady state was attained. Once equilibrium was established, a sample of the boiling liquid and the condensed vapor was taken through a septum using a syringe, to avoid evaporation and to minimize the quantity of sample removed.…”

Vapor-liquid equilibria of the ternary system methyl borate-methyl alcohol-benzene

“…Data for the three binary systems which compose the ternary have been measured and reported previously (8)(9)(10) showing that methyl borate-benzene is an ideal system and the other two have minimum-boiling azeotropes. From the data for these systems binary constants were calculated for the Margules and Wilson equations ( 11).…”

Excess Enthalpies of Alkyl Formates + (n‐Alkanes or 1‐Chloroalkanes). Experimental Data and their Analysis in Terms of the UNIFAC Model

“…The present paper is a continuation of earlier studies by the authors into the thermodynamic properties of binary fluid mixtures composed of esters and various organic sol- [2,3], on excess enthalpies and volumes of alkyl acetates + n-alkanes and aromatic hydrocarbons by Grolier et al [4], on excess enthalpies of propyl acetate and ethyl propanoate + n-alkanes by Navarro et al [S], on excess enthalpies of ethyl acetate and ethyl propanoate + n-alkanols by Navarro et al [6], and on excess volumes of ethyl acetate and propyl acetate + n-alkanols by Ortega et al [7]. Thermodynamic data for binary systems composed of esters + chloroalkanes are not very common in the literature, and earlier papers by the authors have therefore presented data on v E [8,9] and hE [lO,ll], in an attempt to describe the behaviour of such mixtures and to determine the UNIFAC model parameters for the interaction between the C1-group of the chloroalkane and the COOC-group of the ester.…”