Vapor-liquid equilibriums of methyl borate-carbon tetrachloride and methyl borate-benzene systems

Plank, Charles A.; Christopher, Phoebus M.

doi:10.1021/je60069a024

Cited by 10 publications

(10 citation statements)

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“…These solutions, as pointed out previously (3), present a complex behavior that, following cryoscoplc and ultrasonic investigations (3)(4)(5)(6), may be explained on the basis of aggregation phenomena of solvated Ions. The conductivity Is higher for Ca2+ solutions and this fact Is In line with the higher charge of this Ion.…”

supporting

confidence: 58%

Vapor-liquid equilibria of the system trimethyl borate (1)-n-heptane (2)

Niswonger¹,

Plank²,

Laukhuf³

1985

J. Chem. Eng. Data

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supporting

confidence: 58%

Vapor-liquid equilibria of the system trimethyl borate (1)-n-heptane (2)

Niswonger¹,

Plank²,

Laukhuf³

1985

J. Chem. Eng. Data

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“…(2) was used where 7 is in Kelvin and P°in mmHg. This latter equation gives a slightly better representation of the experimental data than the previously reported equation of Plank and Christopher (8).…”

Section: Resultsmentioning

confidence: 67%

“…Data for the three binary systems which compose the ternary have been measured and reported previously (8)(9)(10) showing that methyl borate-benzene is an ideal system and the other two have minimum-boiling azeotropes. From the data for these systems binary constants were calculated for the Margules and Wilson equations ( 11).…”

Section: Resultsmentioning

confidence: 99%

Vapor-liquid equilibria of the ternary system methyl borate-methyl alcohol-benzene

Muenster¹,

Plank²,

Laukhuf³

et al. 1984

J. Chem. Eng. Data

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Vapor-liquid equilibrium measurements at 101325 Pa are reported for the methyl borate-methyl alcohol-benzene system. Analysis of the results shows that the ternary system can be reasonably represented from binary data by the Wilson equations and slightly better by the Margules correlations. The ternary system Is made up of two mlnlmum-boHIng azeotropic systems and one Ideal binary system. No ternary azeotrope exists.

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“…EBID experiments were performed on a silicon substrate (100, n-type, P-doped, native oxide surface, MTI Corporation) with TMB precursor (99.95+%, Strem Chemicals, vapor pressure: 13.7 × 10 3 Pa at 20 °C [ 21 ], thermally stable up to a minimum of 470 °C [ 22 ]) at various substrate temperatures using a custom-built, large-area deposition system ( Fig. 1 ).…”

Section: Methodsmentioning

confidence: 99%

Formation mechanisms of boron oxide films fabricated by large-area electron beam-induced deposition of trimethyl borate

Martin

Depond

2018

Beilstein J. Nanotechnol.

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Boron-containing materials are increasingly drawing interest for the use in electronics, optics, laser targets, neutron absorbers, and high-temperature and chemically resistant ceramics. In this article, the first investigation into the deposition of boron-based material via electron beam-induced deposition (EBID) is reported. Thin films were deposited using a novel, large-area EBID system that is shown to deposit material at rates comparable to conventional techniques such as laser-induced chemical vapor deposition. The deposition rate and stoichiometry of boron oxide fabricated by EBID using trimethyl borate (TMB) as precursor is found to be critically dependent on the substrate temperature. By comparing the deposition mechanisms of TMB to the conventional, alkoxide-based precursor tetraethyl orthosilicate it is revealed that ligand chemistry does not precisely predict the pathways leading to deposition of material via EBID. The results demonstrate the first boron-containing material deposited by the EBID process and the potential for EBID as a scalable fabrication technique that could have a transformative effect on the athermal deposition of materials.

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Vapor-liquid equilibriums of methyl borate-carbon tetrachloride and methyl borate-benzene systems

Cited by 10 publications

References 0 publications

Vapor-liquid equilibria of the system trimethyl borate (1)-n-heptane (2)

Vapor-liquid equilibria of the system trimethyl borate (1)-n-heptane (2)

Vapor-liquid equilibria of the ternary system methyl borate-methyl alcohol-benzene

Formation mechanisms of boron oxide films fabricated by large-area electron beam-induced deposition of trimethyl borate

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