Vapor pressure isotope effect in aqueous systems. I. Water-water-d2 (-64.deg. to 100.deg.) and water-water18-0 (-17.deg. to 16.deg.). Ice and liquid. II. Alkali metal chloride solution in water and water-d2 (-5.deg. to 100.deg.)

Pupezin, J.; Jákli, Gy.; Jancsó, Gábor; Hook, W. Van Alexander

doi:10.1021/j100649a025

Cited by 69 publications

(57 citation statements)

References 6 publications

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“…As seen in Fig. 2, our result on aD is close to that of MAJOUBE (1971) at the higher temperature range, and is close to that of PUPEZIN et al (1972) at the lower temperature range. The temperature dependence of aD given by the present study is similar to that of JONES (1968).…”

Section: Introductionsupporting

confidence: 83%

Direct measurements of D/H and 18O/16O fractionation factors between vapor and liquid water in the temperature range from 10 to 40.DEG.C.

Kakiuchi

Matsuo

1979

Geochem. J.

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Section: Introductionsupporting

confidence: 83%

Direct measurements of D/H and 18O/16O fractionation factors between vapor and liquid water in the temperature range from 10 to 40.DEG.C.

Kakiuchi

Matsuo

1979

Geochem. J.

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“…In the calculation the relative humidity of the surface air is assumed to be 90% and the moist air parcel is assumed to be expanded adiabatically. The fractionation factors used are those compiled by Pupezin et al (1972) for 18O between water vapor and water and also for D, and those measured by Majoube (1970) for 18O between water vapor and ice. Fig.…”

Section: The Oxygen Isotopic Composition Of the Snowmentioning

confidence: 99%

A Chemical Study of Snow Formation in the Winter-monsoon Season: The Contribution of Aerosols and Water Vapor from the Continent

Tsunoga

Fukuda

Nakaya

1975

Journal of the Meteorological Society of Japan

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The snow caused by the winter-monsoon in Japan was analyzed for chemical constituents, radionuclides and stable isotopes. The chloride in the snow was correlated fairly well with not only sodium of maritime origin but also calcium, sulfate and radionuclides for samples collected during a single snowfall. The rainout process seems to be prevailing over the washout process for the removal of the chemical constituents from the convective cloud. The air mass responsible for making 1 kg of snow water was calculated to be about 2000 m3 STP from the radon daughter nuclides 210Pb, 210Bi and 210Po in the snow collected at Assabu, Hokkaido. The isotopic composition of the snow is not controlled directly by the temperatures of the sea surface and of the air where the snow is forming as suggested by Isono et al. (1966) but controlled by the relation among water vapor contents in the continental air and in the air transported to the Pacific and the amount of water vapor evaporated from the Japan Sea. The consistency between these results was quantitatively examined by making the budget diagram of water and chemical substances during the winter-monsoon season.

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“…It is found that the liquidphase pressure and the vapor-phase pressure at the same measured position are on the either side of the extrapolated saturation pressure curve given by Pupezin et al 1 The liquidphase pressure is higher than the extrapolated saturated pressure at the same interfacial liquid temperature. The vaporphase pressure is lower than the extrapolated saturation pressure at the same interfacial vapor temperature.…”

Section: Resultsmentioning

confidence: 59%

“…By definition, the saturation pressure, P sat , at its isothermal liquid temperature, is determined at a flat surface under the equilibrium conditions. The pressure of D 2 O was experimentally measured above the triple point at 276.97 K, [1][2][3][4] whereas the experiments were seldom reported in measuring P sat directly below the triple point. Bottomley measured the vapor-pressure difference between the metastable liquid and the stable solid of D 2 O by using two 0.5 g samples in two connected glass bulbs, respectively, as the temperature was lowered to 261.35 K. 5 However, the assumption of thermal equilibrium might be difficult to reach in the experiments.…”

Section: Introductionmentioning

confidence: 99%

Thermal Properties of Deuterium Oxide near the Triple Point Predicted from Nonequilibrium Evaporation

Duan

Crivoi

2010

J. Chem. Eng. Data

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Statistical rate theory (SRT) was applied to predict the saturation pressure of D 2 O numerically near the triple point based on the interfacial liquid-phase temperature, the interfacial vapor-phase temperature, and the local evaporation flux from 102 local measures in a series of nonequilibrium steady-state droplet evaporation experiments. An analytical expression of the saturation pressure, P sat , was obtained from the predicted values. Following the thermodynamic relations, the specific entropy of evaporation, h fg , and the liquid-phase specific heat at constant pressure, C p L , were computed. The agreement that the calculated values of these properties with those obtained from the independent measurements indicates that the SRT expression accurately predicts the thermal properties of D 2 O near the triple point.

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Vapor pressure isotope effect in aqueous systems. I. Water-water-d2 (-64.deg. to 100.deg.) and water-water18-0 (-17.deg. to 16.deg.). Ice and liquid. II. Alkali metal chloride solution in water and water-d2 (-5.deg. to 100.deg.)

Cited by 69 publications

References 6 publications

Direct measurements of D/H and 18O/16O fractionation factors between vapor and liquid water in the temperature range from 10 to 40.DEG.C.

Direct measurements of D/H and 18O/16O fractionation factors between vapor and liquid water in the temperature range from 10 to 40.DEG.C.

A Chemical Study of Snow Formation in the Winter-monsoon Season: The Contribution of Aerosols and Water Vapor from the Continent

Thermal Properties of Deuterium Oxide near the Triple Point Predicted from Nonequilibrium Evaporation

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