2015
DOI: 10.4236/msce.2015.37009
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Vaporization and Thermodynamics of Glass-Forming Oxide Melts: Mass Spectrometric Study and Modeling

Abstract: Information on the vaporization processes and thermodynamic properties of glass-forming oxide melts in the systems MgO-B2O3-SiO2, CaO-B2O3-SiO2, SrO-B2O3-SiO2, BaO-B2O3-SiO2, PbO-B2O3-SiO2, CdO-B2O3-SiO2, ZnO-B2O3-SiO2, Bi2O3-B2O3-SiO2 and Bi2O3-GeO2-SiO2 together with the earlier obtained data is discussed. These data were obtained by high-temperature mass spectrometric method. Various types of vapor species were found over oxide systems studied such as the associated, dissociated and polymerized products of … Show more

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Cited by 2 publications
(4 citation statements)
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“…Semenov, 5 a number of reviews dealing with the vaporization and thermodynamic properties of oxide systems studied using KEMS at high temperatures have been completed. [185][186][187][188][189][190][191][192][193][194][195][196][197][198][199][200][201][202] The general overview in this area was presented in the series of publications from decade to decade. [185][186][187][188][189][190] We can delineate them into three main groups: glassforming oxide systems, [191][192][193][194][195][196] ultrahigh-refractory oxide systems mainly based on 2, [197][198][199] modeling approaches developed using the Knudsen effusion mass spectrometric thermodynamic data on oxide systems for the prediction of their high-temperature behavior, 189,[193][194][195][196]200,201 and comparison to thermodynamic data that may be obtained at high temperatures using KEMS and differential thermal analysis.…”
Section: Following the Publication Of The Monograph By Stolyarova Andmentioning
confidence: 99%
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“…Semenov, 5 a number of reviews dealing with the vaporization and thermodynamic properties of oxide systems studied using KEMS at high temperatures have been completed. [185][186][187][188][189][190][191][192][193][194][195][196][197][198][199][200][201][202] The general overview in this area was presented in the series of publications from decade to decade. [185][186][187][188][189][190] We can delineate them into three main groups: glassforming oxide systems, [191][192][193][194][195][196] ultrahigh-refractory oxide systems mainly based on 2, [197][198][199] modeling approaches developed using the Knudsen effusion mass spectrometric thermodynamic data on oxide systems for the prediction of their high-temperature behavior, 189,[193][194][195][196]200,201 and comparison to thermodynamic data that may be obtained at high temperatures using KEMS and differential thermal analysis.…”
Section: Following the Publication Of The Monograph By Stolyarova Andmentioning
confidence: 99%
“…Following the publication of the monograph by Stolyarova and Semenov, 5 a number of reviews dealing with the vaporization and thermodynamic properties of oxide systems studied using KEMS at high temperatures have been completed 185–202 . The general overview in this area was presented in the series of publications from decade to decade 185–190 .…”
Section: Measurements Of Partial Pressures and Thermodynamic Properti...mentioning
confidence: 99%
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