1990
DOI: 10.1016/0040-6031(90)80130-q
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Vapour pressure of aqueous tert.-butanol in the water-rich region: transition in the mixing scheme

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Cited by 39 publications
(29 citation statements)
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“…The arrows indicate the apparent laboratory on aqueous solutions of tert-butyl alcohol (heretransition points from mixing schemes 1 to 11 and 11 to 111 for after abbreviated as TBA) (1)(2)(3)(4)(5)16) and 2-butoxyethanol (BE) BE-H,O. (6)(7)(8)(9)(10)(11)(12)(13)(14)(15)(16).…”
mentioning
confidence: 99%
See 1 more Smart Citation
“…The arrows indicate the apparent laboratory on aqueous solutions of tert-butyl alcohol (heretransition points from mixing schemes 1 to 11 and 11 to 111 for after abbreviated as TBA) (1)(2)(3)(4)(5)16) and 2-butoxyethanol (BE) BE-H,O. (6)(7)(8)(9)(10)(11)(12)(13)(14)(15)(16).…”
mentioning
confidence: 99%
“…Using various derivatives including those mentioned above, it was found (1)(2)(3)(4)(5)(6)(7)(8)(9)(10)(11)(12)(13)(14)(15)(16) that the mixing scheme, the way in which the solute A and the solvent H,O mix with each other, changes qualitatively at xTBA = 0.045 for TBA-H,O and at X B E = 0.0175 for BE, both at 25°C. The threshold is characterized by anomalies in all the third derivatives of the Gibbs energy that have been investigated so far, including peaks in HAAE as shown in Fig.…”
mentioning
confidence: 99%
“…The IBA-IBA interaction changes from a repulsive to an attractive mode at about XB = 0.03. This crossover, however, does not seem as drastic as those for TBA (3,14,15) and BE (5,6,16). In other works, the enthalpic solute-solute interaction, the third derivative of the free energy, does not show any anomaly in contrast to the TBA and BE cases.…”
Section: Methodsmentioning
confidence: 82%
“…36. Thus the crossover from low concentration to high concentration mixing scheme in the IBA-H20 system is qualitatively more subtle than those in the TBA-H20 (3,14,15) and BE-H20 (5,6, 16) systems. This must be related to the apparent weakness of the effect of the solvent IBA on the structure of H 2 0 as discussed above.…”
Section: Methodsmentioning
confidence: 92%
“…In an aqueous solution of NEO, the simulation study revealed that enough amount of water molecules sacrifice their hydrogen bonds to accommodate the solute molecule, which facilitates the formation of dangling OH bonds around its surface . The aqueous solution of TBA has been studied extensively by theoretical calculations, integral equation) and various experimental methods including thermodynamics, Raman, X‐ray, neutron, infrared, NMR spectroscopy, and mass spectroscopy . The fs‐IR and Raman measurements unfolded that there was no direct hydrophobic contact between water and monohydric alcohols ranging from methanol to TBA …”
Section: Introductionmentioning
confidence: 99%