Shale gas (SG) wells
in the Wufeng–Longmaxi Formation in
northern Guizhou differ considerably in their production capacities.
Preservation conditions are a crucial factor affecting the formation
of SG reservoirs. In this study, the formation water (FW) in four
wells in northern Guizhou was analyzed to determine the type; the
Cl/Mg, Ca/Mg, and Na/Cl coefficients (C
Cl/Mg, C
Ca/Mg, and C
Na/Cl, respectively), and the coefficient of desulfurization
(C
d); the SG in these wells was tested
to identify its composition and the sources of its components. The
results show the following: wells TX1 and CY1 contain two types (CaCl2 and NaHCO3) of FW, each with low C
Na/Cl, low C
d, high C
Ca/Mg, and high C
Cl/Mg, suggesting a high level of FW retention. The FW in wells TM1 and
CD1 is of NaHCO3 type and is characterized by high C
Na/Cl, high C
d,
low C
Ca/Mg, and low C
Cl/Mg, indicating a high level of connectivity between
the FW and surface water. Nonhydrocarbon gases account for a high
proportion of SG in composition; with a 15N value between
−8.7 and −4.2‰, N2 accounts for approximately
20% of SG in wells TX1 and CY1, respectively. This result indicates
the ammonification of organic matter (OM) during pyrolysis and hydrocarbon
generation as sources of N2. In contrast, with a 15N value between −3.6 and 0‰, N2 accounts
for over 70% of SG in wells TM1 and CD1, respectively, indicating
the atmosphere, the ammonification of OM, and the presence of poor
preservation conditions due to a high level of connectivity between
the shale bed and the atmosphere acted as the sources of N2. The metamorphism coefficients of FW in conjunction with the SG
composition and the sources of nonhydrocarbon gases can serve as auxiliary
indicators of the quality of SG preservation conditions.