Various amide-derived ligands induced five octamolybdate-based metal–organic complexes: synthesis, structure, electrochemical sensing and photocatalytic properties

Abstract

Five octamolybdate-based complexes with diverse architectures employing three new amide-derived organic ligands can be used as promising electrochemical sensors and photocatalysts.

Five new multifunctional inorganic–organic hybrids based on Keggin-type polyoxometalates and a 3,5-di(1H-imidazol-1-yl)benzoic acid ligand

“…For 2-CPE, the peak currents are proportional to the square root of the scan rates, indicating that the redox process is diffusion-confined. 36 However, the peak currents are proportional to the scan rates for 4-and 5-CPEs, indicating that the redox processes are surfaceconfined 35c (Fig. S5 †).…”

Anderson-type polyoxometalate-based sandwich complexes bearing a new “V”-like bis-imidazole-bis-amide ligand as electrochemical sensors and catalysts for sulfide oxidation

“…To S3-S6 in the ESM) [14,34,[38][39][40][41][42][43][44][45][46][47][48][49][50]. By comparing the LODs of 1-3-CPEs for the above ions, the detection ability was found to follow the order 1-CPE > 2-CPE > 3-CPE.…”