Triboelectric nanogenerators
(TENGs) represent intriguing
technology
to harvest human mechanical movements for powering wearable and portable
electronics. Differently, compared to conventional fabrication approaches,
additive manufacturing can allow the fabrication of TENGs with good
dimensional resolution, high reproducibility, and quick production
processes and, in particular, the obtainment of complex and customized
structures. Among 3D printing technologies, digital light processing
(DLP) is well-known for being the most flexible to produce functional
devices by controlling both the geometry and the different ingredients
of printable resins. On the other hand, DLP was not exploited for
TENG fabrication, and consequently, the knowledge of the performance
of 3D printable materials as charge accumulators upon friction is
limited. Here, the application of the DLP technique to the 3D printing
of triboelectric nanogenerators is studied. First, several printable
materials have been tested as triboelectric layers to define a triboelectric
series of DLP 3D printable materials. Then, TENG devices with increased
geometrical complexity were printed, showcasing the ability to harvest
energy from human movement. The method presented in this work illustrates
how the DLP may represent a valuable and flexible solution to fabricate
triboelectric nanogenerators, also providing a triboelectric classification
of the most common photocurable resins.