Weeds remain one of the most important factors affecting the yield and quality of corn in modern agricultural production. To use deep convolutional neural networks to accurately, efficiently, and losslessly identify weeds in corn fields, a new corn weed identification model, SE-VGG16, is proposed. The SE-VGG16 model uses VGG16 as the basis and adds the SE attention mechanism to realize that the network automatically focuses on useful parts and allocates limited information processing resources to important parts. Then the 3 × 3 convolutional kernels in the first block are reduced to 1 × 1 convolutional kernels, and the ReLU activation function is replaced by Leaky ReLU to perform feature extraction while dimensionality reduction. Finally, it is replaced by a global average pooling layer for the fully connected layer of VGG16, and the output is performed by softmax. The experimental results verify that the SE-VGG16 model classifies corn weeds superiorly to other classical and advanced multiscale models with an average accuracy of 99.67%, which is more than the 97.75% of the original VGG16 model. Based on the three evaluation indices of precision rate, recall rate, and F1, it was concluded that SE-VGG16 has good robustness, high stability, and a high recognition rate, and the network model can be used to accurately identify weeds in corn fields, which can provide an effective solution for weed control in corn fields in practical applications.