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a b s t r a c tPaola Ridge, along the NW Calabrian margin (southern Tyrrhenian Sea), is one of the few reported deep sea sites of precipitation of authigenic carbonates in the Tyrrhenian Sea. Here, the changing composition of the seeping fluids and the dynamic nature of the seepage induced the precipitation of pyrite, siderite and other carbonate phases. The occurrence of this array of authigenic precipitates is thought to be related to fluctuation of the sulfate-methane transition zone (SMTZ).Concretions of authigenic minerals formed in the near sub-bottom sediments of the Paola Ridge were investigated for their geochemical and isotopic composition. These concretions were collected in an area characterized by the presence of two alleged mud volcanoes and three mud diapirs. The mud diapirs are dotted by pockmarks and dissected by normal faults, and are known for having been a site of fluid seepage for at least the past 40 kyrs. Present-day venting activity occurs alongside the two alleged mud volcanoes and is dominated by CO 2 -rich discharging fluids. This discover led us to question the hypothesis of the mud volcanoes and investigate the origin of the fluids in each different domed structure of the study area.In this study, we used stable isotopes (carbon and oxygen) of carbonates coupled with rare earth element (REE) composition of different carbonate and non-carbonate phases for tracing fluid composition and early diagenesis of authigenic precipitates. The analyses on authigenic precipitates were coupled with chemical investigation of venting gas and sea-water.Authigenic calcite/aragonite concretions, from surficial sediments on diapiric structures, have depleted values. The siderite REE pattern shows consistent LREE (light REE) fractionation, MREE (medium REE) enrichment and positive Gd and La anomalies. As shown by the REE distribution, the 13 C-depleted composition and their association with chemosymbiotic fauna, calcite/aragonite precipitated at time of moderate to high methane flux close to the seafloor, under the influence of bottom seawater. Authigenic siderite, on the other hand, formed in the subseafloor, during periods of lower gas discharges under prolonged anoxic conditions within sediments in equilibrium with 13 C-rich dissolved inorganic carbon (DIC) and 18 O-rich water, likely related to methanogenesis and intermittent venting of deep-sourced CO 2 .
a b s t r a c tPaola Ridge, along the NW Calabrian margin (southern Tyrrhenian Sea), is one of the few reported deep sea sites of precipitation of authigenic carbonates in the Tyrrhenian Sea. Here, the changing composition of the seeping fluids and the dynamic nature of the seepage induced the precipitation of pyrite, siderite and other carbonate phases. The occurrence of this array of authigenic precipitates is thought to be related to fluctuation of the sulfate-methane transition zone (SMTZ).Concretions of authigenic minerals formed in the near sub-bottom sediments of the Paola Ridge were investigated for their geochemical and isotopic composition. These concretions were collected in an area characterized by the presence of two alleged mud volcanoes and three mud diapirs. The mud diapirs are dotted by pockmarks and dissected by normal faults, and are known for having been a site of fluid seepage for at least the past 40 kyrs. Present-day venting activity occurs alongside the two alleged mud volcanoes and is dominated by CO 2 -rich discharging fluids. This discover led us to question the hypothesis of the mud volcanoes and investigate the origin of the fluids in each different domed structure of the study area.In this study, we used stable isotopes (carbon and oxygen) of carbonates coupled with rare earth element (REE) composition of different carbonate and non-carbonate phases for tracing fluid composition and early diagenesis of authigenic precipitates. The analyses on authigenic precipitates were coupled with chemical investigation of venting gas and sea-water.Authigenic calcite/aragonite concretions, from surficial sediments on diapiric structures, have depleted values. The siderite REE pattern shows consistent LREE (light REE) fractionation, MREE (medium REE) enrichment and positive Gd and La anomalies. As shown by the REE distribution, the 13 C-depleted composition and their association with chemosymbiotic fauna, calcite/aragonite precipitated at time of moderate to high methane flux close to the seafloor, under the influence of bottom seawater. Authigenic siderite, on the other hand, formed in the subseafloor, during periods of lower gas discharges under prolonged anoxic conditions within sediments in equilibrium with 13 C-rich dissolved inorganic carbon (DIC) and 18 O-rich water, likely related to methanogenesis and intermittent venting of deep-sourced CO 2 .
Discoveries from multibeam bathymetry and geochemical surveys performed off Zannone Island (western Pontine Archipelago, Tyrrhenian Sea) provide evidence of an undocumented hydrothermal field characterized by ongoing fluid emissions and morphologically complex giant depressions located in shallow water (<150 m water depth). Based on a detailed morpho‐bathymetric study we identify the seabed morphologies produced by hydrothermal fluid emission activity. We recognize five giant depressions (length >250 m) that host pockmarks, mounds, small cones, and active fluid vents, which are interpreted as complex fluid‐escape features developed both through vigorous‐explosive events and steady seepage. Their spatial distribution suggests that the NE‐SW trending faults bounding the Ponza‐Zannone structural high and the shallow fractured basement are favorable conditions for the upward migration of hydrothermal fluids. Moreover, we performed a detailed geochemical study to investigate the source of the hydrothermal fluids. The geochemical signature of the collected fluids provides information of active CO2‐dominated degassing with a significant contribution of mantle volatiles, with measured 3He/4He values > 3.0 Ra that are similar to those recorded at Stromboli and Panarea volcanoes. The hydrothermal system produces volatiles that may originate from residual magma batches, similar to the Pleistocene trachytes cropping out in the SE sector of Ponza Island that were probably intruded in the shallow crustal levels and never erupted. The discovery of the Zannone hydrothermal field updates the record of active hydrothermal areas of the Mediterranean Sea. Moreover, the recognition of several giant hydrothermal depressions characterized by a complex morphology is peculiar for the Mediterranean Sea.
Submarine cold seeps are widely distributed in the continental margin seas around the world. In this study, we apply a conventional multichannel seismic reflection (seismic oceanography) method to image the water column near the seafloor in order to detect cold seeps. In addition to analyzing the fluid escape structures, we also describe and discuss the development positions, seismic reflection characteristics as well as features of the cold seeps. The seismic reflection from the water column is very weak; therefore, the seismic sections above and below the seafloor are processed in two different sequences as follows: (1) geometry definition, direct wave attenuation and amplitude recovery, high‐pass filter, common midpoint sorting, constant velocity (seawater sound velocity) stack, and post‐stack FK filter in some sections; and (2) data quality control, amplitude recovery, 6∼100 Hz bandpass filter, multiple attenuation, deconvolution, velocity analysis, normal move‐out correction, common midpoint stack, post‐stack noise attenuation, 4∼70 Hz bandpass filter, and FX migration. The processed sections are then assembled together along the seafloor after carefully adjusting the color scale. The analysis shows that active cold seeps primarily present plume, broom, and/or irregular shapes that have weak and chaotic seismic reflections in the water column. The seismic reflection amplitude is enhanced at times; this could be attributed to the suspension of mud or particles in the water column. Cold seepage activities are typically associated with fluid escape structures, including mud diapirs, pipes, faults, fractures, gas chimneys, seabed pockmarks, and mud volcanoes. This indicates fluid migration from deep to shallow strata, fluid seepage or escape at the seafloor, as well as the formation of widespread cold seep activities. All the results herein are derived from a comprehensive interpretation of the seismic sections of the water columns and strata; however, further field studies, theoretical simulations, and experiments are required to confirm these conclusions.
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