Verification of the rate-controlling steps in the hydriding reaction of Mg2Ni

Hydrogen storage properties of Mg100−xNix (x=5, 11.3, 20, 25) composites prepared by hydriding combustion synthesis followed by mechanical milling (HCS+MM)

“…Generally, this mechanical process reduces the grain size and generates a great amount of defects in the lattice that may facilitate both of the hydrogenation and dehydrogenation reaction [2,3]. A number of investigations used this process to synthesize composites by mixing magnesium with additives including elements [4,5], oxides [6,7], organics [8] and intermetallics [9,10].…”

Adsorption Characteristics of LaNi5Particles

“…, FeTi, Mg Ni, and AB -type Laves phase are wellknown hydrogen-storage intermetallic compounds that have been investigated by many researchers (1)(2)(3)(4)(5)(6)(7)(8)(9)(10)(11)(12)(13)(14)(15). Among these intermetallic compounds, LaNi , FeTi, and E Fe , one of the AB -type Laves phases, have equilibrium plateau pressures higher than 1 bar even at 273 K, and therefore the heat necessary for hydrogen evolution can be easily provided from the cooling water used for heat exchange.…”

Adsorption phenomena of a mechanically-alloyed mixture 2Mg+Ni

“…MgzNi, LaNis, FeTi and ABz-type Laves phases are well known hydrogen-storage intermetallic compounds which have been investigated by many researchers [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15]. LaNis, FeTi and ErFe2, one of the AB2-type Laves phases, have the equilibrium plateau pressures higher than 1 bar even under 273 K while Mg2Ni has the equlibrium plateau pressure of 1 bar at 515 K around [16].…”