Verschweißen, Organisieren und „Pflanzen”︁ von organischen Molekülen auf Substratoberflächen: Bottom‐up‐Ansätze in der Nanoarchitektonik

Hydrogen‐Bonding Fingerprints in Electronic States of Two‐Dimensional Supramolecular Assemblies

“…A variety of one-dimensional (1D) and 2D hydrogen-bonded structures have been reported, [4][5][6][7] ranging from homomolecular systems to binary assemblies on well characterized single-crystal surfaces. [8][9][10][11][12] In particular, regular heteromolecular assemblies based upon hydrogen bonding have been successfully formed by coadsorption of molecular species exhibiting complementary functional amine/imide end-groups on nanostructured template substrates, such as vicinal Au(111) surfaces.…”

Peptide–Polymer Hybrid Nanotubes

“…There is an increased use of so‐called bottom‐up strategies for the design of organic nanotubes and nanofibers 6. Some promising examples of this include the self‐assembly of amphiphilic molecules (small lipids,7 di‐8 and triblock,9 and coil‐ring‐coil10 block copolymers), polymeric foldamers,11 as well as the self‐assembly of cyclic peptides to form peptide nanotubes 12–14…”

Mesoporous Platinum with Giant Mesocages Templated from Lyotropic Liquid Crystals Consisting of Diblock Copolymers

“…Templated synthesis of nanostructured metals with tunable composition, structure, and morphology allows us to finely control the metals' properties, which is a typical example of materials nanoarchitectonics that emphasizes the importance of novel size‐ and shape‐dependent properties 1. Traditionally, various nanostructured metals (for example, nanowire arrays,2 bicontinuous nanowire networks,3 nanoparticle arrays4) have been prepared by utilizing hard templates including mesoporous silica.…”