Strongly angular-dependent emission properties are observed from a semiconductor microcavity pumped along a critical angle of incidence. In contrast to the luminescence from conventional semiconductor heterostructures, the emission is completely asymmetrical with respect to the sample normal. The results imply that parametric scattering dominates the energy relaxation of polaritons, and is enhanced by the deformed shape of the dispersion relations.Planar semiconductor microcavities are of considerable interest because they can be used to modify and enhance optical emission from embedded semiconductor heterostructures. Highly controlled light output from microcavity lightemitting diodes ͑LEDs͒ and vertical cavity surface emitting lasers ͑VCSELs͒ is of practical application, 1 while organic microcavities have also successfully supported laser operation.2 When cooled sufficiently, optimally designed semiconductor microcavities enter a regime of strong coupling in which the exciton resonance mixes sufficiently with the cavity photon mode to form two new polariton modes. 3 Recent publications highlight the nonlinear power dependence of the luminescence from such samples and have controversially attributed it to stimulated scattering. [4][5][6][7] However under nonresonant pumping, light from these heterostructures, as from bare quantum wells, remains symmetrically distributed about the normal to the sample.In this paper, we comprehensively characterize both spectrally and angularly, the emission of light from microcavity samples which are resonantly pumped at a critical angle. In this regime strong angular asymmetries are seen in the photoluminescence, produced by parametric scattering between pairs of polaritons with different in-plane momentum and energy. Strong nonlinearities in the emission are produced when this scattering is stimulated by occupation of the final polariton state. By simultaneously injecting a pulse of light incident normally, the parametric scattering is externally stimulated and the two final states clearly observed.Angular measurements on these microcavity polaritons provide crucial information because they probe the whole range of exciton-photon interactions, starting from 0°where the coupling is strong and reaching Ϯ55°where the two modes are effectively not coupled. 8 Our experimental geometry concentrates on resonant pulsed excitation at the point of inflection of the lower polariton dispersion (k ʈ ϭ2.1ϫ10 6 m Ϫ1 ), while detecting the time-integrated luminescence emerging at different angles ͑Fig. 1͒. When the exciton and photon modes are degenerate at ϭ0°( ex ϭ cav ), this pump configuration generates parametric scattering shown by arrows in Fig. 2͑a͒, in which pump polariton pairs at ( p ,k p ) end up at both ( p Ϯ⑀,kϮq).9 To demonstrate the strong sensitivity of this scattering rate to the final state population, a normally incident probe pulse can be set to arrive simultaneously with the pump pulse. In order to inject polaritons at specific (,k), the optical pulses are spectrally fil...