“…Free-standing III–V semiconductor nanowires (NWs) have evolved into a promising material platform with various potential device applications in electronics, optoelectronics, and integrated photonics. − Their tiny footprint enables compatibility with lattice-mismatched substrates, such as silicon (Si), , and the unique one-dimensional (1D) optical cavity structure with a large refractive index contrast facilitates effective confinement and low-loss propagation of optical modes along the NW’s axial direction. , Additionally, the small diameter and lateral relaxation of strain within the NW enable the formation of axial heterostructures well beyond the critical thickness limit of planar structures . Such platform can, thus, realize various 1D heterostructure devices, such as resonant tunneling diodes, , ultrafast photodetectors , and lasers, , terahertz NW quantum cascade lasers, and single-photon sources based on NW quantum dots (NW-QDs). − Particularly, the deterministic nature of single, site-controlled quantum disks or QDs embedded along the NW growth axis offers attractive capabilities beyond those of conventional Stranski–Krastanov growth. Such NW-QDs or -disks have demonstrated great potential as quantum light sources and low-threshold lasers with high material gain due to their intriguing physical properties, including enhanced light–matter interaction and efficient carrier confinement. ,,− It has also been demonstrated that NW-QDs grown along the [111] orientation have a vanishing fine-structure splitting due to their symmetry, which can be ideal candidates for generating entangled photon pairs. , Thus, the realization of high-quality axial heterostructures within III–V NWs, featuring abrupt interfaces and controlled composition, is a crucial step to harnessing the full potential of these nanomaterials for practical applications.…”