As an outstanding member in the oxide nanowire family, ZnO nanowire is widely studied for its optical, semiconductive, and piezoelectric properties. PbZr x Ti 1-x O 3 (PZT), usually in the form of polycrystalline thin films, is known for its high piezoelectric coefficient and is an ideal material as actuator. In this review, we first briefly introduce the rational growth of ZnO and PZT nanowire arrays by seedless wet chemical methods. Utilizing the ordered ZnO nanowires grown on p-type substrates, we next present an array of single ZnO nanowire-based blue/near-UV light-emitting diodes (LEDs), including their fabrication process, electroluminescence (EL) spectra, and external quantum efficiency. Finally, we discuss the piezoelectric ZnO and PZT nanowire-enabled three-dimensionally integrated direct-and alternating-current nanogenerators, and their primary roles in selfpowered nanosystems and for powering personal microelectronics.Oxide nanowire arrays for energy sciences 2173virtue of entropy increase, resulting in higher decomposition rate of HMTA. Therefore, at the initial stage of reaction, HMTA has already decomposed to a relatively large degree and produced sufficient OHfor ZnO growth, so the base of ZnO nanorods is thicker than at lower temperatures. As the supply of Zn 2+ gradually becomes exhausted, the diameter of the nanowire would gradually decrease, forming a pyramidal shape. The ZnO nanowires synthesized via this method are of low aspect ratios, typically 10 to 15 [12], which greatly limits their applications where flexible or high surface-to-volume ratio nanowires are needed. To increase the aspect ratio, capping agents such as ethylenediamine [16] and polyethylenimine [2] can be added. However, these capping agents might also introduce certain impurities into the ZnO nanowires, undermining their properties and performance. Without capping agents, improvement of the aspect ratio proved to be challenging, because reaction parameters such as precursor concentration, growth time, and growth temperature worked together in a convoluted manner toward the final growth product. Most reported studies employed inefficient cook-and-look methods, and lacked theoretical guidance in experimental design. Fig. 2 SEM images of ZnO nanowire arrays with an aspect ratio of (a) 15.1, (b) 20.1, (c) 20.9, and (d) 22.3, respectively, and (e) their corresponding reflectance spectra [15]. Oxide nanowire arrays for energy sciences 2177 Fig. 4 (a) Top view and (b) 60º tilt view of the ZnO nanowire arrays on a GaN substrate. Inset in (a) is enlarged image showing the in-plane alignment of the nanowires. (c) Top view and (d) 60º tilt view of a 200 × 200 μm patterned nanowire array with 1 μm in pitch [20].
Fabrication of the heterostructural LEDWhile the pursuit of stable and reproducible p-ZnO is still ongoing [38], heterojunctions of n-ZnO and p-GaN were employed as an alternative approach considering the similar crystallographic and electronic properties of ZnO and GaN. The design of the LED is shown in Fig. 7a. Ordered ZnO nan...