Vibrational and structural evidence of phase transitions in some amides

Desseyn, H. O.; Clou, K; Janssens, J; Carleer, Robert

doi:10.1016/s0040-6031(02)00540-3

Cited by 2 publications

(1 citation statement)

References 24 publications

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“…Matsuoka and Ozawa [1] pointed out how the number of organic materials being separated and/or purified by crystallization in industrial scale operations is increasing rapidly (low energy consumption and possibility of obtaining products with a higher purity than by other conventional separation operations). However, modeling of organic solidliquid equilibria is not as well developed as for metal oxides or salts, or as well as liquid-gas equilibria, although some recent literature can be found [2][3][4][5][6][7][8]; thus accurate empirical data has to be sought. Whereas several data banks or tools concerning liquid-gas equilibria are available for organic mixtures, it is quite difficult to find data about liquid-solid equilibria.…”

Section: Introductionmentioning

confidence: 99%

Experimental Solid–Liquid Phase Equilibria of a Methyl Ester/Amide/Nitrile Ternary System by DSC

Mekki-Berrada

Bennici

Dubois

et al. 2013

J Americ Oil Chem Soc

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Binary and ternary mixtures of lauric methyl ester, amide and nitrile were investigated by differential scanning calorimetry, in order to determine the solid-liquid phase equilibria of this model for saturated organic systems. Eutectic mixtures were observed and followed in the ternary system, while solid-solid transitions and immiscibility phenomena were also characterized. This system is also of industrial interest for processes in the frame of biomass valorization.

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