2020
DOI: 10.1021/acs.jpca.0c02218
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Vibrational Bands of the 2-Butyn-1-yl Radical

Abstract: The 2-butyn-1-yl radical is an isomer of C 4 H 5 and is structurally similar to the propargyl radical, which is the simplest resonance-stabilized hydrocarbon radical. The C 4 H 5 radical is likely to be important to astrochemistry and combustion, similar to propargyl, yet little research has been done on its spectroscopic properties. In this work, seven vibrational bands of the 2-butyn-1-yl radical are reported. The radical was formed by pyrolysis of 1-bromo-2-butyne at 800 K and isolated in a low-temperature … Show more

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