Vibrational spectra, field of force, and electrochemical parameters of methyl chloromethyl ether

BetIOn. J.-M.; Desmadrll, M.; Mitraki, A.; Yon, J. M. Biochemkby 1984, 23 6654-6681. Craig, S.; Hollecker, M.; Creighton, T. E.; Pain, R. H. J. Mol. Biol. 1985. 185. 681-687. Brems, D. N.; Plaisted, S. M.; Havel, H. A.; Kauffman, E. W.; Stodola, J. D.; Eaton, L. C.; White, R. D. Blochemisby 1985, 24, 7662-7668. Holzman. T. F.; Brems, D. N.; Douaherty. J. J.. Jr. Biochemlst~y 1986, -. 25, 6907-6917. Kuwaiima, K.; Hiraoka, Y.; Ikegushi, M.; Sugai, S. Biochemistry 1985, 24 ~ 074-88 1. Frontlcelli, C.; Bucci, E. Biophys. Chem. 1985, 23, 125-128. Brems, D. N.; Plaisted, S. M.; Dougherty. J. J., Jr.; Holzman. T. F. J. Horwltz, J.; Strkkland, E. H.; Billups, C. J. Am. Chem. SOC. 1970, 24 1 , 449-457. 585-590. 91, 184-190. 3205-32 13. 92, 2119-2129. Havei. H. A.; Kauffman, E. W.; Plaisted, S. M.; Brems, D. N. Biochemistry 1986, 25, 6533-6538. (61) Wlllis, P. R.; Georgalis, Y. Translent infrared emisslon spectroscopy (TIRES) is a newmethod that produces analytically useful emlsslon spectra from optlcally Ihlck, solid samples by greatly reducing selfabsorptlon of emitted radlatlon. The method reduces selfabsorption by creating a thln, short-llved, heated layer at the sample surface and coHectlng the transient emission from thls layer. The techdque requires no sample preparation and may be appiled to both moving and statlonary samples. The slngle-ended, noncontact TIRES measurement geometry is Ideal for on-llne and other remote-senslng applications. TIRES spectra acquired via a Fourler transform infrared spectrometer on movlng samples of coal, plastic, and palnt are presented and compared to photoacoustlc absorptlon spectra of these materlals. The TIRES and photoacoustk results are In close agreement as predlcted by Klrchhoff's law.

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Silver-coated fumed silica as a substrate material for surface-enhanced Raman scattering

Alak¹,

Vo‐Dinh²

1989

Anal. Chem.

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A new and simple type of substrate for surface-enhanced raman scattering (SERS) was investigated. This new substrate Is based upon sliver-coated fumed silica on surfaces such as glass plates or microscopic slides. Fumed silica, which has submicrometer size structure provides the surface roughness necessary for SERS process. The effects of several experimental factors, including the type of fumed silica, the concentration of the microparticles, and the silver layer thickness were Investigated. The SERS spectra of various organic species were used to demonstrate the efficiency and applicability of the new substrate. Fumed-slllca-based substrates offer many advantages, since they are simple to prepare and easy to handle. The basic material, fumed silica, Is also commercially available at very low cost.

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Vibrational spectra, field of force, and electrochemical parameters of methyl chloromethyl ether

Cited by 3 publications

References 5 publications

Band intensities in vibrational spectra and ester structure

Band intensities in vibrational spectra and ester structure

Transient infrared emission spectroscopy

Silver-coated fumed silica as a substrate material for surface-enhanced Raman scattering

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