Vibrational spectra of phenylethynylcopper(I)

Garbusova, I.A.; ALEXANJAN, V. T.; Leites, L. A.; Gol'ding, I. R.; Sladkov, A. M.

doi:10.1016/s0022-328x(00)85026-3

Cited by 26 publications

(7 citation statements)

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“…For the two isostructural chains in 3 and 4 , the bands at 1928 and 1875 cm −1 in 3 and 1948 and 1890 cm −1 in 4 are attributed to the μ,η 1,2 ‐CC bridging modes. Previous infrared and Raman spectroscopic studies also did not support the presence of two chemically different types of CC bonds in the solid‐state structure of [{PhCCCu} ∞ ] and [{PhCCAg} ∞ ] 31a,b. The higher energy band at 2052 cm −1 in 4 is ascribed to asymmetric CC stretching due to weak silver–acetylide interactions 31c.…”

Section: Resultsmentioning

confidence: 90%

Structure Determination of Homoleptic Au^I, Ag^I, and Cu^I Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Chui

Che

2005

Chemistry A European J

220

116

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This article describes the structure determination of five homoleptic d(10) metal-aryl/alkylacetylides [RC triple bond CM] (M=Cu, R=tBu 1, nPr 2, Ph 3; R=Ph, M=Ag 4; Au 5) by using X-ray single-crystal and powder diffraction. Complex 1.C6H6 reveals an unusual Cu20 catenane cluster structure that has various types of tBuC triple bond C-->Cu coordination modes. By using this single-crystal structure as a starting model for subsequent Rietveld refinement of X-ray powder diffraction data, the structure of the powder synthesized from CuI and tBuC triple bond CH was found to have the same structure as 1. Complex 2 has an extended sheet structure consisting of discrete zig-zag Cu4 subunits connected through bridging nPrC triple bond C groups. Complex 3 forms an infinite chain structure with extended Cu-Cu ladders (Cu-Cu=2.49(4)-2.83(2) A). The silver(I) congener 4 is iso-structural to 3 (average Ag-Ag distance 3.11 A), whereas the gold(I) analogue 5 forms a Au...Au honeycomb network with PhC triple bond C pillars (Au-Au=2.98(1)-3.26(1) A). Solid-state properties including photoluminescence, nu(C triple bond C) stretching frequencies and thermal stability of these polymeric systems are discussed in the context of the determined structures.

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Section: Resultsmentioning

confidence: 90%

Structure Determination of Homoleptic Au^I, Ag^I, and Cu^I Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Chui

Che

2005

Chemistry A European J

220

116

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“…IR (KBr) n/cm -1 : (C∫C) 1940 (vw), 1481 (m), 742 (s), 679 (s), 520 (m), 511 (m). 73 Found: C 58.1, H 3.1%. C 8 H 5 Cu requires: C 58.4, H 3.0%.…”

Section: Preparation Of {Cu(c∫cc 6 H 5 )} N (10a)mentioning

confidence: 97%

Transition metal alkynyl complexes by transmetallation from Au(CCAr)(PPh₃) (Ar = C₆H₅or C₆H₄Me-4)

et al. 2009

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Facile acetylide transfer reactions take place between gold(I) complexes Au(C[triple bond]CAr)(PPh3) (Ar = C6H5 or C6H4Me-4) and a variety of representative inorganic and organometallic complexes MXL, (M = metal, X = halide, L, = supporting ligands) featuring metals from groups 8-11, to afford the corresponding metal-alkynyl complexes M(C[triple bond]CR)Ln in modest to good yield. Reaction products have been characterised by spectroscopic methods, and molecular structure determinations are reported for Fe(C[triple bond]CC6H4Me-4)(dppe)Cp, Ru(C[triple bond]CC6H4Me-4)(dppe)Cp*, Ru(C=CCsF,)(l2-O2)(PPh3)Cp*, Ir(C-CC6H4Me-4)(eta2-O2)(CO)(PPh3), Ni(C[triple bond]CC6H4Me-4)(PPh3)Cp and trans-Pt(C[triple bond]CAr)2L2 (Ar = C6H5, L = PPh3; Ar = C6H4Me-4, L = PPh3, PMe3).

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“…Thus, this difference in the IR spectra of Cu 2 C 2 and NaCu 5 (C 2 ) 3 does not exclude a possible structural similarity between both compounds, but as there are also big differences in other ranges of the IR spectra, it is very unlikely that NaCu 5 (C 2 ) 3 represents are crystalline model compound for the unknown structure of Cu 2 C 2 . More similarities are found in the spectra of NaCu 5 (C 2 ) 3 and phenylethynylcopper(I) ( [18,19], see Table 3). For the later only a vague structural model has been given [27], but the general structural features are similar to those found in NaCu 5 (C 2 ) 3 , i.e.…”

Section: Discussionmentioning

confidence: 75%

NaCu₅(C₂)₃: The First Alkali Metal Transition Metal Acetylide with a Three‐dimensional Framework Structure

Cremer

Ruschewitz

2004

Zeitschrift anorg allge chemie

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By heating the red residue of the reaction of NaC 2 H and CuI in liquid ammonia at 463 K for 30 min in a dynamic vacuum orange polycrystalline NaCu 5 (C 2 ) 3 is obtained. The crystal structure was solved and refined from X-ray powder diffraction data (orthorhombic, Pnma, a ϭ 732.80 (2) pm, b ϭ 1099.63(4) pm, c ϭ 726.15(2) pm, Z ϭ 4, R B ϭ 0.030). It consists of a three-dimensional framework of Cu I and C 2 2Ϫ ions with small channels running parallel to [100] and [001]. The sodium ions reside at the inter-NaCu 5 (C 2 ) 3 : das erste Alkalimetallübergangsmetallacetylid mit einer dreidimensionalen Gerüststruktur Inhaltsübersicht. Durch 30-minütiges Erhitzen des roten Rückstands der Reaktion von NaC 2 H mit CuI in flüssigem Ammoniak auf 463 K in einem dynamischen Vakuum wird orangefarbenes polykristallines NaCu 5 (C 2 ) 3 erhalten. Die Kristallstruktur wurde auf Grundlage von Röntgenpulverbeugungsuntersuchungen gelöst und verfeinert (orthorhombisch, Pnma, a ϭ 732,80(2) pm, b ϭ 1099,63(4) pm, c ϭ 726,15(2) pm, Z ϭ 4, R B ϭ 0,030). Sie besteht aus einem dreidimensionalen Netzwerk von Cu I und C 2 2Ϫ -Ionen

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Vibrational spectra of phenylethynylcopper(I)

Cited by 26 publications

References 1 publication

Structure Determination of Homoleptic Au^I, Ag^I, and Cu^I Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Structure Determination of Homoleptic Au^I, Ag^I, and Cu^I Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Transition metal alkynyl complexes by transmetallation from Au(CCAr)(PPh₃) (Ar = C₆H₅or C₆H₄Me-4)

NaCu₅(C₂)₃: The First Alkali Metal Transition Metal Acetylide with a Three‐dimensional Framework Structure

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Vibrational spectra of phenylethynylcopper(I)

Cited by 26 publications

References 1 publication

Structure Determination of Homoleptic AuI, AgI, and CuI Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Structure Determination of Homoleptic AuI, AgI, and CuI Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Transition metal alkynyl complexes by transmetallation from Au(CCAr)(PPh3) (Ar = C6H5or C6H4Me-4)

NaCu5(C2)3: The First Alkali Metal Transition Metal Acetylide with a Three‐dimensional Framework Structure

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Structure Determination of Homoleptic Au^I, Ag^I, and Cu^I Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Structure Determination of Homoleptic Au^I, Ag^I, and Cu^I Aryl/Alkylethynyl Coordination Polymers by X‐ray Powder Diffraction

Transition metal alkynyl complexes by transmetallation from Au(CCAr)(PPh₃) (Ar = C₆H₅or C₆H₄Me-4)

NaCu₅(C₂)₃: The First Alkali Metal Transition Metal Acetylide with a Three‐dimensional Framework Structure