Vibrational spectra of tin(II) oxalate

Wladimirsky, Alejandra; Palacios, Daniel; D’Antonio, María C.; González‐Baró, Ana C.; Baran, Enrique J.

doi:10.1016/j.saa.2010.04.037

Cited by 14 publications

(5 citation statements)

References 12 publications

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“…In fact, the formation of calcium oxalate has been previously associated with the biochemical deterioration of the ceramic body by fungi and lichens, through the precipitation of this compound in the ceramic matrix [48][49][50]. Oxalic acid is used in industry for the sequestration of metal cations [51,52]. Yet, we could not detect the formation of any lead or tin oxalates on the samples, which could be expected due to high concentration of lead and tin of the glaze.…”

Section: M-ramanmentioning

confidence: 71%

Biodeterioration of majolica glazed tiles by the fungus Devriesia imbrexigena

Miller

Phillip

Mirão

et al. 2019

Construction and Building Materials

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h i g h l i g h t s Fungal bioreceptivity and biodeterioration of historical glazed tiles models was studied. Tile models with two different ageing degrees (pristine and artificially aged) were tested. 12-month laboratory colonization experiment was conducted with the tiles inoculated with fungi. Biogenic calcium oxalate compounds were formed due to fungal biodeterioration. Bioreceptivity and biodeterioration was not correlated with ageing degree.

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Section: M-ramanmentioning

confidence: 71%

Biodeterioration of majolica glazed tiles by the fungus Devriesia imbrexigena

Miller

Phillip

Mirão

et al. 2019

Construction and Building Materials

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“…Irrespective of the samples, the XRD patterns (Figure 1a) are in accordance with 45 The FTIR spectra (Figure 1b) are also consistent with that reported for SnC 2 O 4 . 2,46,47 The doublet absorption peaks at 1674 and 1599 cm −1 can be assigned to the asymmetric stretching of OC−O. Additional doublet absorption peaks at 1340 and 1296 cm −1 are that of symmetric stretching.…”

Section: Resultsmentioning

confidence: 98%

Physico-Geometrical Mechanism and Overall Kinetics of Thermally Induced Oxidative Decomposition of Tin(II) Oxalate in Air: Formation Process of Microstructural Tin(IV) Oxide

Kitabayashi

Koga

2014

J. Phys. Chem. C

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This study focuses on the physico-geometrical mechanism and the overall kinetics of the microstructural tin(IV) oxide formation process by the thermally induced oxidative decomposition of tin(II) oxalate in flowing air. Two tin(II) oxalate samples with different morphologies were subjected to a kinetic study involving thermogravimetrical and morphological observations. The reactions exhibited different behaviors at different steps (multistep behaviors); therefore, the overall reactions were resolved into each reaction step using kinetic analyses based on the cumulative kinetic equation. Oxidative decomposition is characterized by a phase boundary controlled reaction initiated by the surface reaction. The formation of the surface product layer at an early stage of the reaction inhibits diffusion of the product and reactant gases. Gaseous diffusion channels are produced via reformulation of the surface product layer by the reaction itself, and the residual reaction advances in the manner of autocatalytic reaction. The kinetic behavior is regulated by the self-generated reaction conditions under specific, transiently formed structural characteristics of the reacting particles, which vary depending on the applied reaction conditions. Therefore, the process control of the oxidative decomposition is an important factor for controlling the microstructure and physicochemical properties of the resulting tin(IV) oxide.

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“…The strong IR band appeared at ~1635 cm −1 could be assigned to the C–O bonds. The splitting of bands may be due to the presence of two groups of C–O units with different bond lengths . The bands appeared below 790 cm −1 may be due to the antisymmetric vibration of Sn–O–Sn mode .…”

Section: Resultsmentioning

confidence: 98%

Structural, Optical, and Magnetic Properties of Nickel‐Doped Tin Dioxide Nanoparticles Synthesized by Solvothermal Method

2016

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We have successfully synthesized Sn 1 -x Ni x O 2 (0.05 ≤ x ≤ 0.15) solid solutions in order to study their structural, optical, and magnetic properties at different Ni concentrations. X-ray diffraction showed monophasic and crystalline tetragonal structure. The shifting of peaks toward higher angle is attributed to the incorporation of Ni 2+ ions in SnO 2 host lattice. Particle growth restrained upon Ni-doping and found to be in the range of 8-12 nm. Ni-doped SnO 2 nanoparticles show blue shift in band gap studies, which is found to be in the range of 3.9-4.1 eV. High surface areas have been achieved for these solid solutions, which come out to be 130, 200, 457, 497, and 680 m 2 /g, respectively. The solid solutions exhibit paramagnetic behavior along with antiferromagnetic exchange coupling.R. Riman-contributing editor Manuscript No. 36898.

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Vibrational spectra of tin(II) oxalate

Cited by 14 publications

References 12 publications

Biodeterioration of majolica glazed tiles by the fungus Devriesia imbrexigena

Biodeterioration of majolica glazed tiles by the fungus Devriesia imbrexigena

Physico-Geometrical Mechanism and Overall Kinetics of Thermally Induced Oxidative Decomposition of Tin(II) Oxalate in Air: Formation Process of Microstructural Tin(IV) Oxide

Structural, Optical, and Magnetic Properties of Nickel‐Doped Tin Dioxide Nanoparticles Synthesized by Solvothermal Method

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