The average photon path-lengths of the emergent radiation from atmospheres in the case of isotropic and Rayleigh scattering in different orders of scattering are compared. The finite homogeneous plane-parallel atmosphere is illuminated by a parallel unpolarized beam and only the external axial field of radiation is considered. The calculations show that the impact of polarization on the average path-lengths is quite considerable, increasing towards the larger orders of scattering and decreasing towards optically thicker atmospheres. For small angles of incidence and reflection, and for small orders of scattering (n < 15), the average path-lengths of both the reflected and transmitted radiation in the case of Rayleigh scattering are always smaller than those in the case of isotropic scattering, if only the atmosphere is optically not very thick. For large angles of incidence and reflection the situation is vice versa.As a by-product of the calculations we ascertained the asymptotic behaviour of the average path-lengths which was quite similar for scalar and vector transfer. When increasing the optical thickness of an atmosphere, the average path-lengths I;" approach the value n and they do not depend on the angular variables any more. The smaller the order of scattering, the smaller the optical thickness at which this starts to happen. While for the total radiation emerging from optically thick atmospheres at 7 = 7 the average path-length is proportional to Tš, the average path-length in different orders of scattering is a linear function of 79.