A new surface treatment method is developed to achieve
total liquid
transfer. The transfer process of a liquid droplet is recorded through
high-speed photography and analyzed via image analysis to investigate
the hydrodynamic interactions. For a pristine PMMA surface, a viscous
and viscoelastic liquid facilitates transfer by increased viscous
and inertial forces and delayed liquid bridge breakage but is limited
by slow contact line slippage. Hydrophobic surface treatments can
increase contact line slippage and the receding angle to achieve transfer
ratios up to 98%. However, pinning and contact angle hysteresis from
surface roughness features limit liquid transfer, especially for smaller
droplets and higher separation velocities. A lubricant-infused surface
treatment with PDMS and a thin layer of less viscous silicone oil
provides a smooth, homogeneous surface with fast slippage, low contact
angle hysteresis, and only a slight oil wetting ridge. Liquid could
then transfer at high ratios (∼99.9%), regardless of droplet
size and separation velocity. Finally, complete transfer liquid from
indented cells is demonstrated to show the potential of this surface
modification method for gravure printing.