Viscometric Study on Binary Liquid Mixtures of Propiophenone With Aniline and N-Alkyl Substituted Anilines, at 303.15 to 318.15 K

Abstract

Densities and viscosities of binary mixtures of Propiophenone with Aniline, N-methylaniline, N, N- dimethylaniline, N, N- diethylaniline were measured over the entire composition range at T = (303.15 to 318.15) K (with 5K interval) and atmospheric pressure. Experimental data were used to calculate the deviation of viscosity Δη, excess Gibb’s free energy G*E activation of viscous flow for each binary system, and these excess thermodynamic properties were fitted to the Redlich-Kister polynomial equation to obtain the fitting coefficients and standard deviations. McAllister’s three-body /four-body interaction models were used for the correlation of viscosity data. The studied systems exhibit good intermolecular interactions due to hydrogen ion transfer and charge dispersion in the carbonyl group and NH2 groups of Aniline and Alkyl Substituted Anilines. Experimental results are useful in various pharmaceutical industries.