Asphaltene-related flow assurance
problems are prevalent in oil
production processes and are at the heart of issues such as the plugging
of pipelines, the damage of rock formations, and the stabilization
of viscous water-in-oil emulsions. A comprehensive understanding of
the interfacial behavior of asphaltenes, from a physical–chemical
perspective, is required for an accurate design of solutions to these
challenges. In this work, we elucidate the deposition dynamics of
various asphaltene subfractions in a porous media microfluidic model.
Extrography fractions from the interlaboratory sample known as PetroPhase
2017 asphaltenes, reported to be a mixture of abundant island and
archipelago motifs, and Wyoming deposit C7 asphaltenes,
known for being island type dominated, are investigated. The deposition
rate increases when the compositional ratio archipelago/island motif
increases for PetroPhase 2017 derived fractions, whereas Wyoming deposit
asphaltenes appear to exhibit stronger aggregation for fractions whose
composition is uniformly island type. In general, the deposition rate
is consistent with the amount of precipitated asphaltenes. However,
the correlation is not merely a linear one and the pore-scale morphology
changes even with similar deposition rates. Estimated diffusivity,
the relative ratio of convection and diffusion, and fluid flow profiles
are used to explain the dynamic growth of the deposit at the pore
scale.