Visible-light-driven selective oxidation of glucose in water with H-ZSM-5 zeolite supported biomimetic photocatalyst

Chen, Rui; Yang, Changjun; Zhang, Quanquan; Zhang, Bingguang; Deng, Kejian

doi:10.1016/j.jcat.2019.04.044

Cited by 42 publications

(25 citation statements)

References 30 publications

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“…Under visible light irradiation, MPzs can activate hydrogen peroxide or oxygen for the selective organic transformation and pollutant degradation. Several kinds of metallothioporphyrazines with different supports were prepared and further applied to the photocatalytic oxidation of glucose, such as H-ZSM-5supported FePz (SBu) 8 (Chen et al, 2019), SnO 2 -supported FePz (SBu) 8 , TiO 2 /HPW/CoPz (Yin et al, 2020), and ZnO-supported CoPzS 8 (Cheng et al, 2019). For example, a TiO 2 /HPW/CoPz biomimetic photocatalyst was synthesized by modifying TiO 2 with HPW and CoPz (Yin et al, 2020).…”

Section: Photocatalytic Oxidation Of Glucosementioning

confidence: 99%

Recent Advances in Photocatalytic Transformation of Carbohydrates Into Valuable Platform Chemicals

et al. 2021

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In response to the less accessible fossil resources and deteriorating environmental problems, catalytic conversion of the abundant and renewable lignocellulosic biomass to replace fossil resources for the production of value-added chemicals and fuels is of great importance. Depolymerization of carbohydrate and its derivatives can obtain a series of C5-C6 monosaccharides (e.g., glucose and xylose) and their derived platform compounds (e.g., HMF and furfural). Selective transformation of lignocellulose using sustainable solar energy via photocatalysis has attract broad interest from a growing scientific community. The unique photogenerated reactive species (e.g., h+, e−, •OH, •O2−, and 1O2), novel reaction pathways as well as the mild reaction conditions make photocatalysis a “dream reaction.” This review is aimed to provide an overview of the up-to-date contributions achieved in the selective photocatalytic transformation of carbohydrate and its derivatives. Photocatalytic methods, properties and merits of different catalytic systems are well summarized. We then put forward future perspective and challenges in this field.

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Section: Photocatalytic Oxidation Of Glucosementioning

confidence: 99%

Recent Advances in Photocatalytic Transformation of Carbohydrates Into Valuable Platform Chemicals

et al. 2021

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“…Production of hexaric acids catalyzed by metals has been of industrial interest since the 1940s [77,78,79,80,81]. Following these antecedent works, several studies have been reported [68,82,83,84,85,86,87,88,89,90,91,92,93,94,95,96,97,98]. Although Pt [76,82,83,84,91,92,97] and Au [68,84,85,86,89,94,95,96] have been used as catalysts frequently, other elements like Ti [87,88], Mn [90], Fe [98], Mo [93], and Pd [91,99] can also be incorporated in catalyst composites.…”

Section: Hexaric Acid Production Using Inorganic Catalystsmentioning

confidence: 99%

“…Following these antecedent works, several studies have been reported [68,82,83,84,85,86,87,88,89,90,91,92,93,94,95,96,97,98]. Although Pt [76,82,83,84,91,92,97] and Au [68,84,85,86,89,94,95,96] have been used as catalysts frequently, other elements like Ti [87,88], Mn [90], Fe [98], Mo [93], and Pd [91,99] can also be incorporated in catalyst composites. Aldohexoses [84,85,86,87,88,90,91,92,93,94,95,97,98], aldohexonic acids [82,83,84], and hexuronic acid [68,89,96], in addition to the corresponding sugar alcohol [76,85], can be starting compounds for the metal-catalyzed production of hexaric acids.…”

Section: Hexaric Acid Production Using Inorganic Catalystsmentioning

confidence: 99%

“…Although Pt [76,82,83,84,91,92,97] and Au [68,84,85,86,89,94,95,96] have been used as catalysts frequently, other elements like Ti [87,88], Mn [90], Fe [98], Mo [93], and Pd [91,99] can also be incorporated in catalyst composites. Aldohexoses [84,85,86,87,88,90,91,92,93,94,95,97,98], aldohexonic acids [82,83,84], and hexuronic acid [68,89,96], in addition to the corresponding sugar alcohol [76,85], can be starting compounds for the metal-catalyzed production of hexaric acids. In addition to the use of oxidants like H 2 O 2 and O 2 , electrochemical [85,90] and photochemical [87,88] oxidation of the substrates has been examined.…”

Section: Hexaric Acid Production Using Inorganic Catalystsmentioning

confidence: 99%

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Production of Hexaric Acids from Biomass

Sakuta

Nakamura

2019

IJMS

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Sugar acids obtained by aldohexose oxidation of both the terminal aldehyde group and the hydroxy group at the other end to carboxyl groups are called hexaric acids (i.e., six-carbon aldaric acids). Because hexaric acids have four secondary hydroxy groups that are stereochemically diverse and two carboxyl groups, various applications of these acids have been studied. Conventionally, hexaric acids have been produced mainly by nitric acid oxidation of aldohexose, but full-scale commercialization has not been realized; there are many problems regarding yield, safety, environmental burden, etc. In recent years, therefore, improvements in hexaric acid production by nitric acid oxidation have been made, while new production methods, including biocatalytic methods, are actively being studied. In this paper, we summarize these production methods in addition to research on the application of hexaric acids.

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“…Due to the properties of high acidity, high thermal stability, and selectivity, zeolites have been successfully used in various catalytic reactions such as catalytic cracking [7], ethanol dehydration reaction [8], hydrogenation reaction [9], oxidation reaction [10], and isomerization reaction [11]. Homogeneous catalysts and zeolites of basic active sites were used in the isomerization reaction of the glucose in fructose and were not successful [12,13].…”

Section: Introductionmentioning

confidence: 99%

Catalytic conversion of glucose in fructose utilizing high-silica zeolite Sn-ZSM-12

Silva

Santos

et al. 2020

Cerâmica

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Tin incorporation in high-silica ZSM-12 zeolite was evaluated using different concentrations of tin and different structure-directing agents (SDA), in order to be used in the glucose isomerization reaction in fructose. The tetraethylammonium hydroxide SDA successfully formed the structure of the high silica zeolite ZSM-12; however, in this system, the addition of Sn prevented the formation of the ZSM-12 zeolite. Therefore, tetraethylammonium bromide was used as SDA, but the syntheses of high-silica ZSM-12 zeolite without and with tin incorporation were not effective. Then methyltriethylammonium chloride was used as SDA, and the high-silica ZSM-12 structure was formed only with the incorporation of tin. The samples with ZSM-12 structure and different concentrations of tin were evaluated in reaction of glucose conversion to fructose. It was found that the sample with the lowest tin content ( Sn / Si = 0 . 005 ) achieved the highest glucose conversion and the highest fructose yield.

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Visible-light-driven selective oxidation of glucose in water with H-ZSM-5 zeolite supported biomimetic photocatalyst

Cited by 42 publications

References 30 publications

Recent Advances in Photocatalytic Transformation of Carbohydrates Into Valuable Platform Chemicals

Recent Advances in Photocatalytic Transformation of Carbohydrates Into Valuable Platform Chemicals

Production of Hexaric Acids from Biomass

Catalytic conversion of glucose in fructose utilizing high-silica zeolite Sn-ZSM-12

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